FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1906932078> ?p ?o ?g. }

• W1906932078 endingPage "50" @default.
• W1906932078 startingPage "36" @default.
• W1906932078 abstract "We utilized a differential mobility analyzer–mass spectrometer (DMA–MS) with a high resolving power (~45) parallel plate DMA to measure the masses and mobilities of positive and negative ions generated in dry, particle free air with a 10 mCi Po-210 α-irradiation source. We are able to chemically identify 6 positive ions and 25 negative ions in spectra. The positive ions detected were generated by protonation, and included protonated acetone (59 Da), protonated bis-(2-ethylhexyl)phthalate (391 Da), and protonated cyclic polydimethylsiloxanes. The negative ions detected were all deprotonated, and included Teflon-derived perfluoralkanoate ions, long chain alcohol derived alkoxide ions, and the nitrate ion, which, despite its low mass and high mobility was the most abundant ion in negative spectra. Most detected ions can be traced back to system components or to compounds used in the manufacture of system components. Though clearly the detected ions are system specific, the conditions employed were similar to those used in many laboratory scale aerosol measurement systems. The mobility–mass relationship for measured ions was compared to prior mass-mobility measurements of ions produced via α-irradiation, as well as to the predictions of gas molecule scattering calculations, which took as inputs semi-emipirical AM1 based structural models. Through this comparison we show that (1) a universal mobility–mass relationship cannot be applied to all ions and (2) for most ions, gas molecule scattering with diffuse scattering rules can be used to accurately predict ion mobilities. Ion spectra collected with the same system but several months apart were also compared, demonstrating that although similar species are detected, the generated ion spectrum can vary over time. Finally, Brownian dynamics simulations with measured polydisperse ion properties were utilized to determine the expected steady-state charge distribution for particles exposed to the measured ions. Via simulations, we find that the presence or absence of the negative nitrate ion has a strong effect on the steady-state charge distribution and that in most systems it is high concentrations of this ion (relative to others) which can bias charge distributions to negative polarity. Conversely, absence of the nitrate ion shifts charge distributions towards the positive mode." @default.
• W1906932078 created "2016-06-24" @default.
• W1906932078 creator A5041700205 @default.
• W1906932078 creator A5045107570 @default.
• W1906932078 creator A5059744573 @default.
• W1906932078 creator A5076202037 @default.
• W1906932078 creator A5089890888 @default.
• W1906932078 date "2015-12-01" @default.
• W1906932078 modified "2023-10-07" @default.
• W1906932078 title "The mass–mobility distributions of ions produced by a Po-210 source in air" @default.
• W1906932078 cites W1965689475 @default.
• W1906932078 cites W1968058309 @default.
• W1906932078 cites W1968533431 @default.
• W1906932078 cites W1971258832 @default.
• W1906932078 cites W1972114850 @default.
• W1906932078 cites W1973043823 @default.
• W1906932078 cites W1973586872 @default.
• W1906932078 cites W1974863411 @default.
• W1906932078 cites W1974968816 @default.
• W1906932078 cites W1975785335 @default.
• W1906932078 cites W1979470784 @default.
• W1906932078 cites W1979497806 @default.
• W1906932078 cites W1982788594 @default.
• W1906932078 cites W1985606146 @default.
• W1906932078 cites W1989567735 @default.
• W1906932078 cites W1992245191 @default.
• W1906932078 cites W1995048806 @default.
• W1906932078 cites W1996363076 @default.
• W1906932078 cites W2000668741 @default.
• W1906932078 cites W2009943397 @default.
• W1906932078 cites W2011304938 @default.
• W1906932078 cites W2013052896 @default.
• W1906932078 cites W2035972956 @default.
• W1906932078 cites W2043512810 @default.
• W1906932078 cites W2044428202 @default.
• W1906932078 cites W2051267411 @default.
• W1906932078 cites W2051963441 @default.
• W1906932078 cites W2052523342 @default.
• W1906932078 cites W2055146558 @default.
• W1906932078 cites W2055553998 @default.
• W1906932078 cites W2059903043 @default.
• W1906932078 cites W2060001574 @default.
• W1906932078 cites W2063044232 @default.
• W1906932078 cites W2071203685 @default.
• W1906932078 cites W2074627137 @default.
• W1906932078 cites W2077029812 @default.
• W1906932078 cites W2077855340 @default.
• W1906932078 cites W2077973224 @default.
• W1906932078 cites W2078272262 @default.
• W1906932078 cites W2078552083 @default.
• W1906932078 cites W2080831589 @default.
• W1906932078 cites W2089267894 @default.
• W1906932078 cites W2091474459 @default.
• W1906932078 cites W2096395172 @default.
• W1906932078 cites W2101468760 @default.
• W1906932078 cites W2104588582 @default.
• W1906932078 cites W2113757827 @default.
• W1906932078 cites W2120426336 @default.
• W1906932078 cites W2120441639 @default.
• W1906932078 cites W2127336290 @default.
• W1906932078 cites W2134571812 @default.
• W1906932078 cites W2140972591 @default.
• W1906932078 cites W2142049053 @default.
• W1906932078 cites W2142675060 @default.
• W1906932078 cites W2153191658 @default.
• W1906932078 cites W2167106679 @default.
• W1906932078 cites W2317840114 @default.
• W1906932078 cites W2323379205 @default.
• W1906932078 cites W2325522531 @default.
• W1906932078 cites W2332668733 @default.
• W1906932078 cites W648537571 @default.
• W1906932078 doi "https://doi.org/10.1016/j.jaerosci.2015.08.004" @default.
• W1906932078 hasPublicationYear "2015" @default.
• W1906932078 type Work @default.
• W1906932078 sameAs 1906932078 @default.
• W1906932078 citedByCount "55" @default.
• W1906932078 countsByYear W19069320782015 @default.
• W1906932078 countsByYear W19069320782016 @default.
• W1906932078 countsByYear W19069320782017 @default.
• W1906932078 countsByYear W19069320782018 @default.
• W1906932078 countsByYear W19069320782019 @default.
• W1906932078 countsByYear W19069320782020 @default.
• W1906932078 countsByYear W19069320782021 @default.
• W1906932078 countsByYear W19069320782022 @default.
• W1906932078 countsByYear W19069320782023 @default.
• W1906932078 crossrefType "journal-article" @default.
• W1906932078 hasAuthorship W1906932078A5041700205 @default.
• W1906932078 hasAuthorship W1906932078A5045107570 @default.
• W1906932078 hasAuthorship W1906932078A5059744573 @default.
• W1906932078 hasAuthorship W1906932078A5076202037 @default.
• W1906932078 hasAuthorship W1906932078A5089890888 @default.
• W1906932078 hasConcept C11174340 @default.
• W1906932078 hasConcept C113196181 @default.
• W1906932078 hasConcept C145148216 @default.
• W1906932078 hasConcept C162356407 @default.
• W1906932078 hasConcept C16291436 @default.
• W1906932078 hasConcept C178790620 @default.
• W1906932078 hasConcept C185592680 @default.

• next