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• W1908483318 endingPage "2369" @default.
• W1908483318 startingPage "2366" @default.
• W1908483318 abstract "A novel method for the synthesis of 1-silyl-substituted 1,3-butadienes, based on [RuHCl(CO)(PCy3)2]-catalyzed silylative coupling of terminal (E)-1,3-dienes with vinylsilanes, is reported. The reaction provides a facile and straightforward access to (E,E)-dienylsilanes in a highly stereoselective fashion (especially for aryl-substituted dienes) and opens a valuable and general synthetic route for the direct catalytic silylation of conjugated dienes with elimination of ethylene as a single byproduct. Preliminary results on synthetic application of the synthesized silylated 1,3-butadienes in desilylation reactions are described." @default.
• W1908483318 created "2016-06-24" @default.
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• W1908483318 date "2015-04-27" @default.
• W1908483318 modified "2023-10-11" @default.
• W1908483318 title "Ruthenium-Catalyzed Silylation of 1,3-Butadienes with Vinylsilanes" @default.
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• W1908483318 doi "https://doi.org/10.1021/acs.orglett.5b00865" @default.
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