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- W1908652823 abstract "Strontium guanidinate, SrC(NH)3, the first compound with a doubly deprotonated guanidine unit, was synthesized from strontium and guanidine in liquid ammonia and characterized by X-ray and neutron diffraction, IR spectroscopy, and density-functional theory including harmonic phonon calculations. The compound crystallizes in the hexagonal space group P63/m, constitutes the nitrogen analogue of strontium carbonate, SrCO3, and its structure follows a layered motif between Sr2+ ions and complex anions of the type C(NH)32−; the anions adopt the peculiar trinacria shape. A comparison of theoretical phonons with experimental IR bands as well as quantum-chemical bonding analyses yield a first insight into bonding and packing of the formerly unknown anion in the crystal." @default.
- W1908652823 created "2016-06-24" @default.
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- W1908652823 date "2015-08-26" @default.
- W1908652823 modified "2023-10-16" @default.
- W1908652823 title "Synthesis, Structure, and Properties of SrC(NH)<sub>3</sub>, a Nitrogen-Based Carbonate Analogue with the Trinacria Motif" @default.
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- W1908652823 doi "https://doi.org/10.1002/anie.201507113" @default.
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