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- W1908788232 abstract "Amination of 4-nitrophenol, umbelliferone and 4-methylumbelliferone gave the corresponding oxyamines 1–3. These oxyamines react with aldehydes and ketones to form oximes. In the case of aliphatic aldehydes and electron-poor aromatic aldehydes, the oximes undergo base-catalyzed fragmentation in aqueous buffer in the presence of bovine serum albumin to give the parent phenols, which is the acyclic analog of Kemp's elimination reaction of 5-nitrobenzisoxazole 28. The process can be used as a spectrophotometric assay for formaldehyde under aqueous neutral conditions." @default.
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- W1908788232 date "2004-01-01" @default.
- W1908788232 modified "2023-10-17" @default.
- W1908788232 title "Aldehyde detection by chromogenic/fluorogenic oxime bond fragmentationElectronic supplementary information (ESI) available: NMR spectra. See http://www.rsc.org/suppdata/ob/b4/b400314d/" @default.
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- W1908788232 doi "https://doi.org/10.1039/b400314d" @default.
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