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- W1909174550 abstract "In this article, we show how neutron reflectometry (NR) can provide deep insight into the absorption and desorption properties of commercially promising hydrogen storage materials. NR benefits from the large negative scattering length of hydrogen atoms, which changes the reflectivity curve substantially, so that NR can determine not only the total amount of stored hydrogen but also the hydrogen distribution along the film normal, with nanometer resolution. To use NR, the samples must have smooth surfaces, and the film thickness should range between 10 and 200 nm. We performed a systematic study on thin Mg 1– x Al x alloy films (x = 0.2, 0.3, 0.4, 0.67) capped with a Pd catalyst layer. Our NR experiments showed that Mg 0.7 Al 0.3 is the optimum alloy composition with the highest amount of stored hydrogen and the lowest desorption temperature. All the thin films expand by about 20% because of hydrogen absorption, and the hydrogen is stored only in the MgAl layer with no hydrogen content in the Pd layer." @default.
- W1909174550 created "2016-06-24" @default.
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- W1909174550 date "2010-10-01" @default.
- W1909174550 modified "2023-10-16" @default.
- W1909174550 title "A systematic neutron reflectometry study on hydrogen absorption in thin Mg<sub>1-</sub><i><sub>x</sub></i>Al<i><sub>x</sub></i> alloy films Special issue on Neutron Scattering in Canada." @default.
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- W1909174550 doi "https://doi.org/10.1139/p09-085" @default.
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