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- W1909669451 abstract "The spectra of the ν1, 2ν1–ν1, ν2, 2ν2, and 3ν2–ν2 bands of CF4 were obtained with a quasi-continuous wave stimulated Raman spectrometer. These five bands were studied at a temperature of 135 and 300 K (for the hot bands). The spectrum of ν1 was obtained at a sample pressure of 2 mbar. For the spectra of the other regions, which are much weaker, higher pressures were used. The analysis has been performed thanks to the xtds and spview softwares developed in Dijon for such highly symmetric molecules. Combining the present results with a previous infrared study, we could determine a very accurate value for the C–F equilibrium bond length, i.e. re = 1.31588(6) Å. Copyright © 2013 John Wiley & Sons, Ltd." @default.
- W1909669451 created "2016-06-24" @default.
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- W1909669451 creator A5065087830 @default.
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- W1909669451 date "2013-02-03" @default.
- W1909669451 modified "2023-10-04" @default.
- W1909669451 title "High-resolution stimulated Raman spectroscopy and analysis of the <i>ν</i> <sub>1</sub> , 2<i>ν</i> <sub>1</sub> -<i>ν</i> <sub>1</sub> , <i>ν</i> <sub>2</sub> , 2<i>ν</i> <sub>2</sub> , and 3<i>ν</i> <sub>2</sub> -<i>ν</i> <sub>2</sub> bands of CF<sub>4</sub>" @default.
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- W1909669451 doi "https://doi.org/10.1002/jrs.4248" @default.
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