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- W1910040942 abstract "Polyorganosiloxane containing phthalocyaninatocobalt(II) in the side chain (PCPMSTACo(II)Pc) (4) was synthesized from poly[(3-carboxypropyl)methylsiloxane] (PCPMS) (1) and 2,9,16,23-tetraaminophthalocyaninatocobalt(II) (TACo(II)Pc) (3). The wavelength of maximum absorption of TACo(II)Pc in PCPMS-TACo(II)Pc in solution of N,N-dimethylformamide (DMF) is shifted depending on the polymer environment. From UV/VIS spectra of PCPMS-TACo(II)Pc, most of the phthalocyanine moieties in PCPMS-TACo(II)Pc may be expected to exist monomeric in methanol as well as in DMF. The glass transition temperature (Tg) of PCPMS-TACo(II)Pc is high compared with that of PCPMS and the maximum Tg is 50°C. Further, the formation of a crosslinked film is reported, and in this film most of the phthalocyanine moieties may be expected to exist dimeric as concluded from the UV/VIS spectrum. This dimer formation and intramolecular bridges between TACo(II)Pc and carboxyl groups are considered to influence Tg, because they reduce the mobility of the main chains." @default.
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- W1910040942 date "1989-09-01" @default.
- W1910040942 modified "2023-09-27" @default.
- W1910040942 doi "https://doi.org/10.1002/macp.1989.021900931" @default.
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