Matches in SemOpenAlex for { <https://semopenalex.org/work/W1911304003> ?p ?o ?g. }
Showing items 1 to 94 of
94
with 100 items per page.
- W1911304003 endingPage "1401" @default.
- W1911304003 startingPage "1396" @default.
- W1911304003 abstract "The coordination behaviour of the heterofunctional phosphine ligand PPh2NHC(O)Me towards Rh(I) is reported and examples of neutral and cationic complexes containing mono- or bi-dentate modes of coordination are found. The X-ray structure of [Rh{PPh2NHC(O)Me}(CO)Cl]·CH2Cl2 (1·CH2Cl2) shows that the P,O-chelate is almost planar and coplanar with the Rh(I) square-plane. An unusual example of coordination is found in the dimer [Rh{μ-PPh2NC(O)Me}(CO)]2 (2), which contains the bidentate, anionic ligand that bridges two rhodium atoms via the oxygen; it is probable that the neutral ligand can form similar complexes, such as 11 and 12. Displacement of the P,O ligand by CO or RNC ligands occurs in 1 but not in 2." @default.
- W1911304003 created "2016-06-24" @default.
- W1911304003 creator A5062360713 @default.
- W1911304003 creator A5063605867 @default.
- W1911304003 creator A5064059180 @default.
- W1911304003 creator A5074142100 @default.
- W1911304003 creator A5087146731 @default.
- W1911304003 date "2003-02-19" @default.
- W1911304003 modified "2023-09-25" @default.
- W1911304003 title "Rhodium complexes containing the hybrid P,O ligand PPh2NHC(O)Me or its anion, [PPh2NC(O)Me]–Dedicated to Dr Jean-Marie Basset on the occasion of his 60th birthday, with our congratulations and best wishes." @default.
- W1911304003 cites W1592241744 @default.
- W1911304003 cites W1979699202 @default.
- W1911304003 cites W1991663245 @default.
- W1911304003 cites W1999042687 @default.
- W1911304003 cites W1999112652 @default.
- W1911304003 cites W2032728742 @default.
- W1911304003 cites W2034483067 @default.
- W1911304003 cites W2035825680 @default.
- W1911304003 cites W2054725947 @default.
- W1911304003 cites W2073881108 @default.
- W1911304003 doi "https://doi.org/10.1039/b208735a" @default.
- W1911304003 hasPublicationYear "2003" @default.
- W1911304003 type Work @default.
- W1911304003 sameAs 1911304003 @default.
- W1911304003 citedByCount "28" @default.
- W1911304003 countsByYear W19113040032012 @default.
- W1911304003 countsByYear W19113040032013 @default.
- W1911304003 countsByYear W19113040032016 @default.
- W1911304003 countsByYear W19113040032017 @default.
- W1911304003 countsByYear W19113040032018 @default.
- W1911304003 countsByYear W19113040032020 @default.
- W1911304003 countsByYear W19113040032021 @default.
- W1911304003 crossrefType "journal-article" @default.
- W1911304003 hasAuthorship W1911304003A5062360713 @default.
- W1911304003 hasAuthorship W1911304003A5063605867 @default.
- W1911304003 hasAuthorship W1911304003A5064059180 @default.
- W1911304003 hasAuthorship W1911304003A5074142100 @default.
- W1911304003 hasAuthorship W1911304003A5087146731 @default.
- W1911304003 hasConcept C115624301 @default.
- W1911304003 hasConcept C116569031 @default.
- W1911304003 hasConcept C145148216 @default.
- W1911304003 hasConcept C161790260 @default.
- W1911304003 hasConcept C170493617 @default.
- W1911304003 hasConcept C178516000 @default.
- W1911304003 hasConcept C178790620 @default.
- W1911304003 hasConcept C179104552 @default.
- W1911304003 hasConcept C183882617 @default.
- W1911304003 hasConcept C185592680 @default.
- W1911304003 hasConcept C188027245 @default.
- W1911304003 hasConcept C197404232 @default.
- W1911304003 hasConcept C2777716191 @default.
- W1911304003 hasConcept C2779546866 @default.
- W1911304003 hasConcept C521398313 @default.
- W1911304003 hasConcept C55493867 @default.
- W1911304003 hasConcept C71240020 @default.
- W1911304003 hasConcept C8010536 @default.
- W1911304003 hasConceptScore W1911304003C115624301 @default.
- W1911304003 hasConceptScore W1911304003C116569031 @default.
- W1911304003 hasConceptScore W1911304003C145148216 @default.
- W1911304003 hasConceptScore W1911304003C161790260 @default.
- W1911304003 hasConceptScore W1911304003C170493617 @default.
- W1911304003 hasConceptScore W1911304003C178516000 @default.
- W1911304003 hasConceptScore W1911304003C178790620 @default.
- W1911304003 hasConceptScore W1911304003C179104552 @default.
- W1911304003 hasConceptScore W1911304003C183882617 @default.
- W1911304003 hasConceptScore W1911304003C185592680 @default.
- W1911304003 hasConceptScore W1911304003C188027245 @default.
- W1911304003 hasConceptScore W1911304003C197404232 @default.
- W1911304003 hasConceptScore W1911304003C2777716191 @default.
- W1911304003 hasConceptScore W1911304003C2779546866 @default.
- W1911304003 hasConceptScore W1911304003C521398313 @default.
- W1911304003 hasConceptScore W1911304003C55493867 @default.
- W1911304003 hasConceptScore W1911304003C71240020 @default.
- W1911304003 hasConceptScore W1911304003C8010536 @default.
- W1911304003 hasIssue "7" @default.
- W1911304003 hasLocation W19113040031 @default.
- W1911304003 hasOpenAccess W1911304003 @default.
- W1911304003 hasPrimaryLocation W19113040031 @default.
- W1911304003 hasRelatedWork W2015656248 @default.
- W1911304003 hasRelatedWork W2021209255 @default.
- W1911304003 hasRelatedWork W2023806430 @default.
- W1911304003 hasRelatedWork W2024208100 @default.
- W1911304003 hasRelatedWork W2028205066 @default.
- W1911304003 hasRelatedWork W2031053324 @default.
- W1911304003 hasRelatedWork W2131417775 @default.
- W1911304003 hasRelatedWork W2133491622 @default.
- W1911304003 hasRelatedWork W2149469070 @default.
- W1911304003 hasRelatedWork W2495369954 @default.
- W1911304003 isParatext "false" @default.
- W1911304003 isRetracted "false" @default.
- W1911304003 magId "1911304003" @default.
- W1911304003 workType "article" @default.