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- W1911573193 abstract "[119062-03-2] C12H14BF4I (MW 371.65)InChI = 1S/C12H14I.BF4/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;2-1(3,4)5/h1,3-4,7-9H,2,5-6,10H2;/q+1;-1InChIKey = WVGOQWISBFCCLQ-UHFFFAOYSA-N(reagent used as a cyclohexyne precursor or as a highly activated iodoalkene)Physical Data: mp 53 °C.Solubility: CH2Cl2, CHCl3, THF, and most alcohols.Form Supplied in: colorless crystals.Purification: colorless crystals recrystallized at −20 °C from a dichloromethane–hexane mixture or a dichloromethane–ether (1/2) mixture.Handling, Storage, and Precautions: stored under argon at −20 °C.Analysis of Reagent Purity: purity is analyzed by 1H NMR (CDCl3): δ 8.02–7.98 (m, 2H), 7.66 (tt, J = 7.49 Hz, J = 1.60 Hz, 1H), 7.54–7.47 (m, 2H), 7.04–7.00 (m, 1H), 2.64–2.58 (m, 2H), 2.47–2.40 (m, 2H), 1.84–1.76 (m, 2H), 1.72–1.63 (m, 2H); 13C NMR (75 MHz, CDCl3) δ 147.7, 135.7, 132.9, 132.5, 119.6, 108.5, 34.5, 30.2, 25.8, 20.4; IR: 3061, 2939, 2864, 1566, 1472, 1444, 1326, 1261, 1064, 745 cm−1; MS (FAB) calculated for C12H14I+ ([M-BF4]+) 285.Preparative Methods: the hypervalent iodine(III) reagent 2 was first synthesized by Ochiai et al.1 Treatment of cyclohexenyltrimethylsilane 1 and iodosobenzene in CH2Cl2 followed by subsequent addition of BF3·OEt2 and a saturated aqueous solution of NaBF4 gave the title compound in 94% yield (eq 1). (1)" @default.
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- W1911573193 date "2011-09-15" @default.
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- W1911573193 title "1-Cyclohexen-1-ylphenyliodonium Tetrafluoroborate" @default.
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- W1911573193 doi "https://doi.org/10.1002/047084289x.rn01364" @default.
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