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- W1912540618 abstract "The photophysical properties of gold nanoparticles, AuNPs, with sizes of 13, 50 and 100 nm in diameter, coated with surface-active ruthenium complexes have been studied to investigate the effect of the distance of the ruthenium luminescent centre from the gold surface. Luminescence lifetimes of the three ruthenium probes, <bold>RuS1</bold>, <bold>RuS6</bold> and <bold>RuS12</bold>, with different length spacer units between the surface active groups and the ruthenium centre were taken. The metal complexes were attached to <bold>AuNP13</bold>, <bold>AuNP50</bold> and <bold>AuNP100</bold><italic>via</italic> thiol groups using a method of precoating the nanoparticles with a fluorinated surfactant. The luminescence lifetime of the longer spacer unit complex, <bold>RuS12</bold>, was enhanced by 70% upon attachment to the AuNP when compared to the increase of the short and medium linker unit complexes, <bold>RuS1</bold> (20%) and <bold>RuS6</bold> (40%) respectively. The effect of the surfactant in the lifetime increase of the ruthenium coated AuNPs was shown to be larger for the medium spacer probe, <bold>RuS6</bold>. There was no effect of the change of the size of the AuNPs from 13 to 50 or 100 nm." @default.
- W1912540618 created "2016-06-24" @default.
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- W1912540618 date "2015-01-01" @default.
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- W1912540618 title "Highly luminescent gold nanoparticles: effect of ruthenium distance for nanoprobes with enhanced lifetimes" @default.
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- W1912540618 doi "https://doi.org/10.1039/c5fd00108k" @default.
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