Matches in SemOpenAlex for { <https://semopenalex.org/work/W1915062416> ?p ?o ?g. }
- W1915062416 abstract "[17257-71-5] C10H9F3O3 (MW 234.19)InChI = 1S/C10H9F3O3/c1-16-9(8(14)15,10(11,12)13)7-5-3-2-4-6-7/h2-6H,1H3,(H,14,15)/t9-/m0/s1InChIKey = JJYKJUXBWFATTE-VIFPVBQESA-N(determination of enantiomeric purity and absolute configuration of alcohols and amines1)Alternate Name: MTPA.Physical Data: bp 115–117 °C/1.5 mmHg; [α]D −71.8° (c 3.28, MeOH); d 1.344 g cm−3.Solubility: readily sol hexane, ether, THF, CH2Cl2, benzene.Form Supplied in: both enantiomers are commercially available and generally possess similar applications.Preparative Methods: both enantiomers are available by resolution of the racemic acid with α-phenylethylamine.1 Other procedures have been described.2Analysis of Reagent Purity: the enantiomeric purity of the reagent can be evaluated by capillary GC analysis of its methyl ester on a chiral stationary phase,3 HPLC analysis of the corresponding 1-(α-naphthyl)ethylamide,2 or by LiAlH4 reduction to the corresponding alcohol, which is analyzed by chiral GC.4Handling, Storage, and Precautions: very stable; commercial samples remain useful after extended periods of time." @default.
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- W1915062416 date "2001-04-15" @default.
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- W1915062416 title "(S)-(−)-α-Methoxy-α-(trifluoromethyl)phenylacetic Acid" @default.
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- W1915062416 doi "https://doi.org/10.1002/047084289x.rm126" @default.
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