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• W1915484163 abstract "The sulfide La4Cd4In2S13 in the quaternary RE/M/N/Q (RE = rare-earth metal; M = Zn, Cd; N = Ga, In; Q = chalcogenides) system was prepared from stoichiometric mixtures of the elements by solid-state reactions at 1223 K in an evacuated silica tube. The La4Cd4In2S13, crystallizing in the Pbam space group, is isostructural with Pb4Bi4In2S13. The structure of La4Cd4In2S13 consists of double chains of CdS6 octahedra extending along [001] direction that are interconnected by single chains of InS6 octahedra by edge-sharing into 1D ribbons. These ribbons are further fused by the infinite one-dimensional chains of InS4 tetrahedra by corner-sharing into Z-shaped [Cd4In2S13]12– layers perpendicular to the b direction separated by the La3+ ions. UV/Vis/NIR diffuse reflectance spectroscopy study shows its optical gap of around 2.27 eV." @default.
• W1915484163 created "2016-06-24" @default.
• W1915484163 creator A5022469389 @default.
• W1915484163 date "2015-07-14" @default.
• W1915484163 modified "2023-09-27" @default.
• W1915484163 title "Synthesis, Crystal Structure, and Optical Property of the Quaternary Semiconductor La4Cd4In2S13" @default.
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• W1915484163 doi "https://doi.org/10.1002/zaac.201500211" @default.
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