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- W1915818184 abstract "The stable phase in the Zn 3 (PO 4 ) 2 –Zn 3 (VO 4 ) 2 system near 25 mol% Zn 3 (VO 4 ) 2 is monoclinic with space group C2/c and unit cell parameters a = 15.941(6), b = 5.314(2), c = 8.265(2) Å, β = 106.96(3)° and Z = 4. The structure was refined by full-matrix least-squares methods using 910 reflections, R = 0.073. The composition, Zn 3 P 1.50 V 0.50(4) O 8 , was determined by site population analysis with the V and P randomly distributed. One-third of the zinc ions lie on twofold axes and these show an average Zn—O bond length of 1.955 Å while the remaining ZnO 4 group has a mean Zn—O bond length of 1.948 Å. The structure consists of sheets parallel to (100) formed of chains containing rings of corner shared Zn(1)O 4 and (V,P)O 4 tetrahedra. The Zn(2)O 4 groups, in turn, form chains parallel to the b axis through corner sharing." @default.
- W1915818184 created "2016-06-24" @default.
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- W1915818184 date "1975-12-01" @default.
- W1915818184 modified "2023-09-26" @default.
- W1915818184 title "Crystal Structure of Zn3V0.5P1.5O8" @default.
- W1915818184 doi "https://doi.org/10.1139/v75-529" @default.
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