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• W1916344977 endingPage "7577" @default.
• W1916344977 startingPage "7565" @default.
• W1916344977 abstract "Lithium-doped spinels could function as solid state electrolytes in batteries in which all components have the spinel structure. In this study we prepared lithium-doped MgAl2O4 and ZnAl2O4. Advanced solid state 7Li, 25Mg, and 27Al NMR have been used to investigate the structure of these spinels and the structural changes that take place therein upon lithium doping. The spinel structure is well retained, although the amount of tetrahedral aluminum increases with increased lithium content. Using MQMAS experiments, the presence of two tetrahedral sites is discovered in both doped and undoped spinels. It is shown that the spinel structure of MgAl2O4 is heterogeneous, which leads to distributions in chemical shift and quadrupolar parameters. The heterogeneity is also shown in 25Mg spectra obtained with the quadrupolar Carr–Purcell–Meiboom–Gill (QCPMG) and sideband selective Double Frequency Sweep-QCPMG (ssDFS-QCPMG) pulse sequences. Lithium mobility is measured using static variable temperature 7Li NMR experiments. A low fraction of mobile lithium was found (3–4%) for magnesium spinels. The lithium doped ZnAl2O4 sample shows practically no mobility. This sample has significantly less disorder and less cation site inversion than the magnesium samples." @default.
• W1916344977 created "2016-06-24" @default.
• W1916344977 creator A5018464728 @default.
• W1916344977 creator A5030253796 @default.
• W1916344977 creator A5033341472 @default.
• W1916344977 date "2015-03-26" @default.
• W1916344977 modified "2023-09-30" @default.
• W1916344977 title "Lithium Doping of MgAl₂O₄ and ZnAl₂O₄ Investigated by High-Resolution Solid State NMR" @default.
• W1916344977 cites W1543800107 @default.
• W1916344977 cites W1851695522 @default.
• W1916344977 cites W1950004664 @default.
• W1916344977 cites W1965181368 @default.
• W1916344977 cites W1969204149 @default.
• W1916344977 cites W1970118513 @default.
• W1916344977 cites W1973623615 @default.
• W1916344977 cites W1974112393 @default.
• W1916344977 cites W1974899616 @default.
• W1916344977 cites W1975948012 @default.
• W1916344977 cites W1977949514 @default.
• W1916344977 cites W1980990112 @default.
• W1916344977 cites W1984099483 @default.
• W1916344977 cites W1986455958 @default.
• W1916344977 cites W1988177701 @default.
• W1916344977 cites W1989571463 @default.
• W1916344977 cites W1993087359 @default.
• W1916344977 cites W1996135148 @default.
• W1916344977 cites W1997393957 @default.
• W1916344977 cites W1997910080 @default.
• W1916344977 cites W1998177977 @default.
• W1916344977 cites W2002100136 @default.
• W1916344977 cites W2003209258 @default.
• W1916344977 cites W2005145460 @default.
• W1916344977 cites W2006386558 @default.
• W1916344977 cites W2006612611 @default.
• W1916344977 cites W2007641411 @default.
• W1916344977 cites W2008421844 @default.
• W1916344977 cites W2011175663 @default.
• W1916344977 cites W2014202794 @default.
• W1916344977 cites W2014751497 @default.
• W1916344977 cites W2015005440 @default.
• W1916344977 cites W2015636561 @default.
• W1916344977 cites W2017265410 @default.
• W1916344977 cites W2020100694 @default.
• W1916344977 cites W2025811002 @default.
• W1916344977 cites W2027633441 @default.
• W1916344977 cites W2030815655 @default.
• W1916344977 cites W2033057654 @default.
• W1916344977 cites W2036808909 @default.
• W1916344977 cites W2038018597 @default.
• W1916344977 cites W2040229488 @default.
• W1916344977 cites W2042289096 @default.
• W1916344977 cites W2045776977 @default.
• W1916344977 cites W2045875631 @default.
• W1916344977 cites W2051630835 @default.
• W1916344977 cites W2051894667 @default.
• W1916344977 cites W2052006574 @default.
• W1916344977 cites W2053080564 @default.
• W1916344977 cites W2060063815 @default.
• W1916344977 cites W2064116220 @default.
• W1916344977 cites W2066256873 @default.
• W1916344977 cites W2069863776 @default.
• W1916344977 cites W2075616010 @default.
• W1916344977 cites W2076209388 @default.
• W1916344977 cites W2080609124 @default.
• W1916344977 cites W2081219991 @default.
• W1916344977 cites W2082875739 @default.
• W1916344977 cites W2084519938 @default.
• W1916344977 cites W2089715220 @default.
• W1916344977 cites W2091403016 @default.
• W1916344977 cites W2092774628 @default.
• W1916344977 cites W2093054032 @default.
• W1916344977 cites W2093521865 @default.
• W1916344977 cites W2094124058 @default.
• W1916344977 cites W2095016731 @default.
• W1916344977 cites W2100061873 @default.
• W1916344977 cites W2102048377 @default.
• W1916344977 cites W2104600715 @default.
• W1916344977 cites W2113202869 @default.
• W1916344977 cites W2122268344 @default.
• W1916344977 cites W2125484471 @default.
• W1916344977 cites W2134792364 @default.
• W1916344977 cites W2135152832 @default.
• W1916344977 cites W2135622132 @default.
• W1916344977 cites W2143795526 @default.
• W1916344977 cites W2144736610 @default.
• W1916344977 cites W2150063329 @default.
• W1916344977 cites W2153511586 @default.
• W1916344977 cites W2161260823 @default.
• W1916344977 cites W2325110810 @default.
• W1916344977 cites W2416869542 @default.
• W1916344977 cites W2501472079 @default.
• W1916344977 cites W2952105934 @default.
• W1916344977 cites W33652711 @default.
• W1916344977 cites W4376848340 @default.
• W1916344977 doi "https://doi.org/10.1021/jp512304e" @default.
• W1916344977 hasPublicationYear "2015" @default.
• W1916344977 type Work @default.
• W1916344977 sameAs 1916344977 @default.

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