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- W1916844437 abstract "Abstract The cyclopentadienyl (Cp) group is a very important ligand for many transition‐metal complexes which have been applied in catalysis. The availability of chiral cyclopentadienyl ligands (Cp x ) lags behind other ligand classes, thus hampering the investigation of enantioselective processes. We report a library of chiral Cp x Ir III complexes equipped with an atropchiral Cp scaffold. A robust complexation procedure reliably provides Cp x Ir III complexes with tunable counterions. In a proof‐of‐concept application, the iodide‐bearing members are shown to be highly selective for enyne cycloisomerization reactions. The dehydropiperidine‐fused cyclopropane products are formed in good yields and enantioselectivities." @default.
- W1916844437 created "2016-06-24" @default.
- W1916844437 creator A5008160159 @default.
- W1916844437 creator A5017497850 @default.
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- W1916844437 date "2015-08-27" @default.
- W1916844437 modified "2023-10-18" @default.
- W1916844437 title "Chiral Cyclopentadienyl Iridium(III) Complexes Promote Enantioselective Cycloisomerizations Giving Fused Cyclopropanes" @default.
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- W1916844437 doi "https://doi.org/10.1002/anie.201506483" @default.
- W1916844437 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26310394" @default.
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