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- W191688854 abstract "X-ray-absorption near-edge structure (XANES) spectra at the Pr ${mathit{L}}_{mathrm{III}}$ threshold were studied for tetravalent ${mathrm{PrO}}_{2}$ as a function of external pressure up to ensuremath{simeq}117 kbar. The observed spectral changes of the double-peaked white line reflect an increase of the Pr 4f/O 2p covalency with pressure, in analogy to previous results for tetravalent ${mathrm{CeO}}_{2}$ and ${mathrm{CeF}}_{4}$. A splitting of the white-line component at the highest energy into two peaks, revealed in the second derivatives of the measured XANES spectra, is interpreted as arising from crystal-field interaction of the 5d states." @default.
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- W191688854 date "1994-01-01" @default.
- W191688854 modified "2023-10-16" @default.
- W191688854 title "X-ray-absorption study of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>PrO</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>at high pressure" @default.
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- W191688854 doi "https://doi.org/10.1103/physrevb.49.39" @default.
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