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- W191701178 abstract "Two examples of “surface-to-bulk” spillover phenomena found for the catalysis of solid heteropolyacids (HPA) are described. (1) By the spillover of hydrogen atom from Pd-carbon into the solid bulk of HPA, the reduction proceeded smoothly at room temperature. A two-step mechanism was confirmed for the reduction of HPA. The reducibility of HPA thus measured exhibited a fair correlation with the catalytic activity for oxidation. (2) The H2 + D2 reaction over HPA at 573 K was shown to belong to bulk-type(II) catalysis. The dissociation of H2 on the surface of HPA and its migration into the solid bulk are rapid, the water formation in the bulk being rate limiting. This was confirmed quantitatively by the analysis of H2 + D2 reactions." @default.
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- W191701178 date "1993-01-01" @default.
- W191701178 modified "2023-10-17" @default.
- W191701178 title "Surface-to-bulk spillover of hydrogen (proton) in the catalysis of solid heteropoly compounds" @default.
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- W191701178 doi "https://doi.org/10.1016/s0167-2991(08)63160-2" @default.
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