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- W1917382832 abstract "A study involving scope in the condensation reaction of phenylsulfonylacetic acid with a series of carbonyl derivatives has been conducted. Reactivity trends favor formation of the corresponding vinyl sulfones when working with aryl aldehydes. Electron-deficient aryl aldehydes outperform electron-rich aryl aldehydes. Negligible differences were noted when using electron-rich and electron-deficient arylsulfonylacetic acid derivatives. Post-run analyses of the reaction mixture reveal formation of a minor product which resulted from methylidene transfer onto the carbonyl derivative. Support of a Knoevenagel-type condensation followed by decarboxylation is provided." @default.
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- W1917382832 date "2015-05-18" @default.
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- W1917382832 title "Phenylsulfonylacetic acid: condensations onto aryl aldehydes" @default.
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- W1917382832 doi "https://doi.org/10.1080/17415993.2015.1043303" @default.
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