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• W1918047034 abstract "A new di-Schiff base ligand has been prepared from 3-acetylpyridine and 1,2-diaminoethane and its structure has also been characterized by single crystal X-ray diffraction. Furthermore, the ligand was found to form a 1 : 1 complex with Ag(NO3) in CH3CN. The crystal structure of the complex exhibits a 1D-double helix with the pitch length of 10 Å. In these reactions, the ligand was found to disintegrate into the individual components to form a crystal of a 3D-network which comprised of Ag(NO3) and 1,2-diamino ethane. Nitrate ions occupied the channels and form several N–H⋯O hydrogen bonds with the walls of the channels. Interestingly, the topology of the 3D-network was found to be similar to that of the CdSO4. This structure prompted us to study the reactions of Ag(NO3) with 1,2-diaminoethane, 1,2-diaminopropane and 1,3-diaminopropane. The crystal structures of these complexes reveal that 1,2-diaminoethane forms the 3D-network similar to the above reaction, whereas 1,2-diaminopropane and 1,3-diaminopropane form a ladder and 1D-zigzag chain, respectively." @default.
• W1918047034 created "2016-06-24" @default.
• W1918047034 creator A5037742035 @default.
• W1918047034 creator A5045246849 @default.
• W1918047034 date "2004-01-01" @default.
• W1918047034 modified "2023-10-16" @default.
• W1918047034 title "Coordination polymers of Ag(i) with di-Schiff base and diaminoalkanes: double helix, ladder, CdSO4 and zigzag-chain networksElectronic supplementary information (ESI) available: Fractional coordinates, full list of bond lengths, angles, anisotropic displacement parameters and ORTEP drawings. See http://www.rsc.org/suppdata/ce/b4/b412903b/" @default.
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• W1918047034 doi "https://doi.org/10.1039/b412903b" @default.
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