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- W1918740966 abstract "Ion mobility spectrometry techniques (IMS and IMS-IMS) combined with collision-induced dissociation (CID) and mass spectrometry (MS) are used to investigate the structures of singly-lithiated carbohydrate isomers. With the exception of some favorable cases, IMS-MS analyses of underivatized carbohydrates reveal that most isobaric precursor ions have similar collision cross sections (ccs). In contrast, ccs values for isomeric fragment ions obtained by IMS-CID-IMS-MS analysis are often different, and thus appear to be useful as a means of distinguishing the isomeric precursors. We report values of ccs (in He) for precursor- and associated-fragment ions for three monosaccharide isomers (glucose, galactose and fructose), ten disaccharide isomers (sucrose, leucrose, palatinose, trehalose, cellobiose, β-gentiobiose, isomaltose, maltose, lactose and melibiose), and three trisaccharide isomers (raffinose, melezitose and maltotriose). These values are discussed as a means of differentiating precursor carbohydrates." @default.
- W1918740966 created "2016-06-24" @default.
- W1918740966 creator A5007958104 @default.
- W1918740966 creator A5035539267 @default.
- W1918740966 creator A5066138229 @default.
- W1918740966 date "2015-01-01" @default.
- W1918740966 modified "2023-09-30" @default.
- W1918740966 title "Investigating carbohydrate isomers by IMS-CID-IMS-MS: precursor and fragment ion cross-sections" @default.
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- W1918740966 doi "https://doi.org/10.1039/c5an00840a" @default.
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