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- W1919129621 abstract "The stereochemistry and the reaction rates of bimolecular nucleophilic substitution reactions involving azides in ionic liquids are governed by solute-solvent interactions. Two-dimensional ultrafast vibrational spectroscopy (2D-IR) shows that the picosecond dynamics of inorganic azides are substantially slower than organic azides in a series of homologous imidazolium ionic liquids. In water, both organic and inorganic azides spectrally diffuse with a ∼2 ps time constant. In the aprotic solvent tetrahydrofuran, both kinds of azides spectrally diffuse on a timescale >5 ps. In ionic liquids, like 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF4]), organic azides spectrally diffuse with a 2-4 ps time constant, and inorganic azides spectrally diffuse with a >40 ps time constant. Such a striking difference suggests that neutral (organic) and charged (inorganic) azides are incorporated in the ionic liquids with different solvation structures." @default.
- W1919129621 created "2016-06-24" @default.
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- W1919129621 date "2015-01-01" @default.
- W1919129621 modified "2023-10-11" @default.
- W1919129621 title "Two-dimensional ultrafast vibrational spectroscopy of azides in ionic liquids reveals solute-specific solvation" @default.
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- W1919129621 doi "https://doi.org/10.1039/c5cp02119g" @default.
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