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• W1919172205 endingPage "142" @default.
• W1919172205 startingPage "111" @default.
• W1919172205 abstract "Carbocycles with various ring sizes are very frequently found in chemical materials and fine chemicals. Polycyclic arenes that are annulated with a cyclooctatetraene (COT, 1), unit form a class of interesting and important species in both theoretical and synthetical aspects. This chapter focuses on the synthesis and application of [8]annulenes, dehydro[8]annulenes, tetraphenylenes, and [8]circulenes derived from COT (1) with different degrees of ring fusion. It reviews the synthesis and properties of some bent p-conjugated systems comprised of benzo-fused[8]annulenes, excluding those with COT rings coordinated to metals. The chapter then talks about tetrabenzo[a,c,e,g]cyclooctene (tetraphenylene) and its derivatives. It delineates the general approaches toward the syntheses of tetraphenylenes. The authors believe that eight-membered carbocycles and derivatives will be synthesized in the near future, and their interesting structural character and unique electrical properties will attract increasing attention from various branches of chemistry including materials science." @default.
• W1919172205 created "2016-06-24" @default.
• W1919172205 creator A5025707880 @default.
• W1919172205 creator A5067319529 @default.
• W1919172205 creator A5072525785 @default.
• W1919172205 date "2015-09-12" @default.
• W1919172205 modified "2023-09-26" @default.
• W1919172205 title "Polycyclic Arenes Containing Eight‐Membered Carbocycles" @default.
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