FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1919736021> ?p ?o ?g. }

• W1919736021 abstract "The reaction of [Os3(CO)10(MeCN)2] with 4-methylthiazole at room temperature gave [Os3(µ-H)(CO)10(µ-2,3-η2-[graphic omitted])]1, in which the thiazolide ligand is co-ordinated to the cluster through the nitrogen and carbon atoms of the CN bond, in high yield. Compound 1 reacted with PPh3 at 110 °C to give [Os3(µ-H)(CO)9(µ-2,3-η2-[graphic omitted])(PPh3)]2 and [Os3(µ-H)(CO)8(µ-2,3-η2-[graphic omitted])(PPh3)2]3. Compound 2 exists as two isomers in solution whereas 3 exists as four. The reaction of 2 with PPh3 at 110 °C yielded 3 in good yield. Compound 1 reacted with 4-methylthiazole at 110 °C to give [Os3(µ-H)2(CO)8(µ-2,3-η2-[graphic omitted])(µ-1,5-η2-[graphic omitted])]4 and [Os3(µ-H)2(CO)8(µ-2,3-η2-[graphic omitted])2]5. In 4 the second thiazolide ligand is co-ordinated through the sulfur and C(5) carbon atoms whereas in 5 both ligands are co-ordinated through the nitrogen and C(2) carbon atoms. The reaction of [Ru3(CO)12] with 1 equivalent of 4-methylthiazole in the presence of sodium–benzophenone at 67 °C gave [Ru3(µ-H)(CO)10(µ-2,3-η2-[graphic omitted])]6 whereas with 2 equivalents it gave [Ru3(µ-H)2(CO)8(µ-2,3-η2-[graphic omitted])2]7. Compounds 6 and 7 are the structural analogues of 1 and 4 respectively. The reaction of 6 with 1 equivalent of 4-methylthiazole in the presence of sodium–benzophenone gave 7. All the compounds were characterized by 1H NMR and infrared spectroscopy and elemental analysis. In addition, the solid-state structures for 1–3 were determined." @default.
• W1919736021 created "2016-06-24" @default.
• W1919736021 creator A5012312112 @default.
• W1919736021 creator A5031648520 @default.
• W1919736021 creator A5043856480 @default.
• W1919736021 creator A5059773332 @default.
• W1919736021 creator A5069132426 @default.
• W1919736021 creator A5073122188 @default.
• W1919736021 creator A5075360098 @default.
• W1919736021 creator A5076417335 @default.
• W1919736021 creator A5079134086 @default.
• W1919736021 creator A5085452573 @default.
• W1919736021 date "1996-01-01" @default.
• W1919736021 modified "2023-09-27" @default.
• W1919736021 title "Triosmium and triruthenium clusters containing the 4-methylthiazolide ligand: crystal structures of [Os3(µ-H)(CO)10(µ-2,3-η2-CNCMeCHS)], [Os3(µ-H)(CO)9(µ-2,3-η2-CNCMeCHS)(PPh3)] and [Os3(µ-H)(CO)8(µ-2,3-η2-CNCMeCHS)(PPh3)2]" @default.
• W1919736021 cites W1558433776 @default.
• W1919736021 cites W1562573840 @default.
• W1919736021 cites W1587888696 @default.
• W1919736021 cites W1964934358 @default.
• W1919736021 cites W1965246521 @default.
• W1919736021 cites W1966835431 @default.
• W1919736021 cites W1967170128 @default.
• W1919736021 cites W1985776474 @default.
• W1919736021 cites W1992193099 @default.
• W1919736021 cites W1992240767 @default.
• W1919736021 cites W1996922203 @default.
• W1919736021 cites W2001216978 @default.
• W1919736021 cites W2002196887 @default.
• W1919736021 cites W2008697225 @default.
• W1919736021 cites W2012566470 @default.
• W1919736021 cites W2017183017 @default.
• W1919736021 cites W2017940459 @default.
• W1919736021 cites W2018240110 @default.
• W1919736021 cites W2018869485 @default.
• W1919736021 cites W2026296608 @default.
• W1919736021 cites W2031303086 @default.
• W1919736021 cites W2032966489 @default.
• W1919736021 cites W2037343022 @default.
• W1919736021 cites W2041659909 @default.
• W1919736021 cites W2042831590 @default.
• W1919736021 cites W2057968492 @default.
• W1919736021 cites W2059245256 @default.
• W1919736021 cites W2060174495 @default.
• W1919736021 cites W2065965655 @default.
• W1919736021 cites W2073126549 @default.
• W1919736021 cites W2073806368 @default.
• W1919736021 cites W2080465782 @default.
• W1919736021 cites W2081903355 @default.
• W1919736021 cites W2083308379 @default.
• W1919736021 cites W2088078886 @default.
• W1919736021 cites W2101748147 @default.
• W1919736021 cites W2148066840 @default.
• W1919736021 cites W2197829671 @default.
• W1919736021 cites W289892631 @default.
• W1919736021 cites W2950016078 @default.
• W1919736021 cites W3137080995 @default.
• W1919736021 cites W3139211392 @default.
• W1919736021 doi "https://doi.org/10.1039/dt9960001731" @default.
• W1919736021 hasPublicationYear "1996" @default.
• W1919736021 type Work @default.
• W1919736021 sameAs 1919736021 @default.
• W1919736021 citedByCount "20" @default.
• W1919736021 countsByYear W19197360212014 @default.
• W1919736021 countsByYear W19197360212018 @default.
• W1919736021 crossrefType "journal-article" @default.
• W1919736021 hasAuthorship W1919736021A5012312112 @default.
• W1919736021 hasAuthorship W1919736021A5031648520 @default.
• W1919736021 hasAuthorship W1919736021A5043856480 @default.
• W1919736021 hasAuthorship W1919736021A5059773332 @default.
• W1919736021 hasAuthorship W1919736021A5069132426 @default.
• W1919736021 hasAuthorship W1919736021A5073122188 @default.
• W1919736021 hasAuthorship W1919736021A5075360098 @default.
• W1919736021 hasAuthorship W1919736021A5076417335 @default.
• W1919736021 hasAuthorship W1919736021A5079134086 @default.
• W1919736021 hasAuthorship W1919736021A5085452573 @default.
• W1919736021 hasConcept C116569031 @default.
• W1919736021 hasConcept C134121241 @default.
• W1919736021 hasConcept C170493617 @default.
• W1919736021 hasConcept C185592680 @default.
• W1919736021 hasConcept C191897082 @default.
• W1919736021 hasConcept C192562407 @default.
• W1919736021 hasConcept C55493867 @default.
• W1919736021 hasConcept C71240020 @default.
• W1919736021 hasConceptScore W1919736021C116569031 @default.
• W1919736021 hasConceptScore W1919736021C134121241 @default.
• W1919736021 hasConceptScore W1919736021C170493617 @default.
• W1919736021 hasConceptScore W1919736021C185592680 @default.
• W1919736021 hasConceptScore W1919736021C191897082 @default.
• W1919736021 hasConceptScore W1919736021C192562407 @default.
• W1919736021 hasConceptScore W1919736021C55493867 @default.
• W1919736021 hasConceptScore W1919736021C71240020 @default.
• W1919736021 hasLocation W19197360211 @default.
• W1919736021 hasOpenAccess W1919736021 @default.
• W1919736021 hasPrimaryLocation W19197360211 @default.
• W1919736021 hasRelatedWork W1759754727 @default.
• W1919736021 hasRelatedWork W1970849471 @default.
• W1919736021 hasRelatedWork W1981771402 @default.
• W1919736021 hasRelatedWork W1985776474 @default.
• W1919736021 hasRelatedWork W1989422454 @default.
• W1919736021 hasRelatedWork W1992193099 @default.

• next