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• W1920331491 abstract "K2ZnGeO4 belongs to the ‘stuffed’ cristobalite structural type. The α-form (SG Pca21) changes to β-form (SG F 3m) above 1049 K by a displacive/rotational transformation with ferroelectric/ferroelastic character, in which the strain is only coupled with the order parameter. The distortion leading from β-HT to α-LT form results from important strains and geared rotations of the ZnO4 and GeO4 tetrahedra. The broad permittivity peak around the transition temperature is typical of a first-order transition. A comparison with isotypic compounds shows that the covalency of the structural skeleton plays a major role in the transition phenomenon." @default.
• W1920331491 created "2016-06-24" @default.
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• W1920331491 date "2006-03-01" @default.
• W1920331491 modified "2023-10-18" @default.
• W1920331491 title "Ferroic phase transitions in K2ZnGeO4and related compounds" @default.
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• W1920331491 doi "https://doi.org/10.1080/01411590500513693" @default.
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