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• W1921060854 abstract "A new imino-N-heterocyclic carbene ligand precursor [1-(2,4,6-Me3C6H2)imidazolium-3-{CH2C(t-Bu)N(i-Pr)}] bromide has been synthesised and structurally characterised. The silver(I) complex [Ag(C⁁imine)2]AgBr2, where (C⁁imine) = 1-(2,4,6-Me3C6H2)imidazol-2-ylidene-3-{CH2C(t-Bu)N(i-Pr)}, was readily prepared by reaction with Ag2O. Transfer of the ligand from silver(I) to palladium(II) and rhodium(I) by reaction with [PdCl2(MeCN)2] and [Rh(cod)(THF)2][BF4] led to the tautomerisation of the imine moiety to the enamine affording the structurally characterised complex [PdCl2(C⁁enamine)] and [Rh(cod)(C⁁enamine)][BF4] respectively, where (C⁁enamine) = 1-(2,4,6-Me3C6H2)imidazol-2-ylidene-3-{CHC(t-Bu)NH(i-Pr)}." @default.
• W1921060854 created "2016-06-24" @default.
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• W1921060854 date "2003-01-01" @default.
• W1921060854 modified "2023-09-27" @default.
• W1921060854 title "Silver(<scp>i</scp>) complex of a new imino-N-heterocyclic carbene and ligand transfer to palladium(<scp>ii</scp>) and rhodium(<scp>i</scp>)" @default.
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• W1921060854 doi "https://doi.org/10.1039/b304474b" @default.
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