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• W1922999747 abstract "Extraction of insoluble metallofullerenes, [email protected]2n (n = 36–38), was conducted with dichlorobenzene, chlorobenzene, and iodobenzene as a solvent under reflux condition. When iodobenzene was used, [email protected]2n (n = 36–38) was successfully extracted as the corresponding phenyl adducts, such as [email protected]72(C6H5), [email protected]74(C6H5), and [email protected]76(C6H5). The number of isomers of corresponding adducts, [email protected]72(C6H5) and [email protected]74(C6H5), were reduced to one-third of that in 1,2,4-trichlorobenzene extracts, which was reported previously. Based on the spectroscopic analysis, the carbon cages of [email protected]72(C6H5) and [email protected]74(C6H5) were deduced to be [email protected]C2(10612)-C72(C6H5) and [email protected]D3h-C74(C6H5), respectively. The addition site carbon possessing very high radical character suggests that the corresponding adducts were produced by the addition of phenyl radical generated from iodobenzene on metallofullerenes." @default.
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• W1922999747 date "2016-03-01" @default.
• W1922999747 modified "2023-10-16" @default.
• W1922999747 title "Effective derivatization and extraction of insoluble missing lanthanum metallofullerenes La@C2n (n = 36–38) with iodobenzene" @default.
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• W1922999747 doi "https://doi.org/10.1016/j.carbon.2015.10.088" @default.
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