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- W1923061444 abstract "We use the method of the most probable distribution to show that the entropy for a general ensemble can be expressed by the maximum value of the disorder function of information theory, derived in Chapter 15 , subject to the set of constraints appropriate to the ensemble. We illustrate this in detail for a grand canonical ensemble with two kinds of particles. We treat a number of other ensembles practically by inspection, including an ensemble that relates to a Massieu function that is the Legendre transform of the entropy. By using a degeneracy factor to sum over energy levels, particle numbers, and volumes, we show that all ensembles can be related in a similar way to their associated thermodynamic functions, as observed by Hill." @default.
- W1923061444 created "2016-06-24" @default.
- W1923061444 creator A5039336322 @default.
- W1923061444 date "2015-01-01" @default.
- W1923061444 modified "2023-10-17" @default.
- W1923061444 title "Entropy for Any Ensemble" @default.
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- W1923061444 doi "https://doi.org/10.1016/b978-0-12-803304-3.00022-3" @default.
- W1923061444 hasPublicationYear "2015" @default.
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