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• W1925544603 abstract "Mesostructured and mesoporous boroaluminophosphates (BAPO's) were synthesised using cationic templating in the presence of boric acid. The products were characterised by X-ray diffraction, 27Al, 31P and 11B solid-state NMR, thermal and elemental analysis, and nitrogen adsorption. Boron is incorporated into the structure, leading to a decrease in the degree of condensation of the inorganic component and to reduced thermal stability. Both tetrahedral and trigonal B is present in the structure of as-synthesised and calcined BAPO, but the B(4)–B(3) ratio is significantly reduced upon calcination. The kinetics of product formation were studied, and the likely mechanism of the synthesis is suggested, involving the formation of boroaluminophosphate oligomers which then react with the surfactant cations." @default.
• W1925544603 created "2016-06-24" @default.
• W1925544603 creator A5072135471 @default.
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• W1925544603 date "2002-02-28" @default.
• W1925544603 modified "2023-09-23" @default.
• W1925544603 title "Synthesis and characterisation of mesoporous aluminophosphates containing boronElectronic supplementary information (ESI) available: thermogravimetric analysis of mesostructured BAPO,XRD patterns of Hex-2 BAPO,27Al MAS NMR spectra of intermediate products formed during the synthesis of Hex-1 BAPO, 11B MAS NMR spectra of Hex-2 BAPO. See http://www.rsc.org/suppdata/jm/b1/b106911j/" @default.
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• W1925544603 doi "https://doi.org/10.1039/b106911j" @default.
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