FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1925979205> ?p ?o ?g. }

• W1925979205 endingPage "18801" @default.
• W1925979205 startingPage "18790" @default.
• W1925979205 abstract "Chemical events that lead to thermal initiation and spontaneous ignition of the high-pressure phase of RDX are presented using reactive molecular dynamics simulations. In order to initiate the chemistry behind thermal ignition, approximately 5% of RDX crystal is subjected to a constant temperature thermal pulse for various time durations to create a hot spot. After application of the thermal pulse, the ensuing chemical evolution of the system is monitored using reactive molecular dynamics under adiabatic conditions. Thermal pulses lasting longer than certain time durations lead to the spontaneous ignition of RDX after an incubation period. For cases where the ignition is observed, the incubation period is dominated by intermolecular and intramolecular hydrogen transfer reactions. Contrary to the widely accepted unimolecular models of initiation chemistry, N-N bond dissociations that produce NO2 species are suppressed in the condensed phase. The gradual temperature and pressure increase in the incubation period is accompanied by the accumulation of short-lived, heavier polyradicals. The polyradicals contain intact triazine rings from the RDX molecules. At certain temperatures and pressures, the polyradicals undergo ring-opening reactions, which fuel a series of rapid exothermic chemical reactions leading to a thermal runaway regime with stable gas-products such as N2, H2O and CO2. The evolution of the RDX crystal throughout the thermal initiation, incubation and thermal runaway phases observed in the reactive simulations contains a rich diversity of condensed-phase chemistry of nitramines under high-temperature/pressure conditions." @default.
• W1925979205 created "2016-06-24" @default.
• W1925979205 creator A5037024512 @default.
• W1925979205 creator A5064447926 @default.
• W1925979205 date "2015-01-01" @default.
• W1925979205 modified "2023-09-26" @default.
• W1925979205 title "Reactive simulation of the chemistry behind the condensed-phase ignition of RDX from hot spots" @default.
• W1925979205 cites W1521219362 @default.
• W1925979205 cites W1542742801 @default.
• W1925979205 cites W1969604626 @default.
• W1925979205 cites W1979680610 @default.
• W1925979205 cites W1995004740 @default.
• W1925979205 cites W2000032215 @default.
• W1925979205 cites W2005693207 @default.
• W1925979205 cites W2006920611 @default.
• W1925979205 cites W2008645489 @default.
• W1925979205 cites W2010398598 @default.
• W1925979205 cites W2019465613 @default.
• W1925979205 cites W2021310745 @default.
• W1925979205 cites W2023912002 @default.
• W1925979205 cites W2024079527 @default.
• W1925979205 cites W2026096289 @default.
• W1925979205 cites W2037137276 @default.
• W1925979205 cites W2040266357 @default.
• W1925979205 cites W2048726254 @default.
• W1925979205 cites W2051254306 @default.
• W1925979205 cites W2054777589 @default.
• W1925979205 cites W2060667292 @default.
• W1925979205 cites W2063384380 @default.
• W1925979205 cites W2067103342 @default.
• W1925979205 cites W2073243165 @default.
• W1925979205 cites W2084669314 @default.
• W1925979205 cites W2094324634 @default.
• W1925979205 cites W2124236867 @default.
• W1925979205 cites W2155155530 @default.
• W1925979205 cites W2159752439 @default.
• W1925979205 cites W2312608514 @default.
• W1925979205 cites W2320565857 @default.
• W1925979205 cites W2324004073 @default.
• W1925979205 cites W2409946133 @default.
• W1925979205 cites W2498841003 @default.
• W1925979205 doi "https://doi.org/10.1039/c5cp00950b" @default.
• W1925979205 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26123323" @default.
• W1925979205 hasPublicationYear "2015" @default.
• W1925979205 type Work @default.
• W1925979205 sameAs 1925979205 @default.
• W1925979205 citedByCount "28" @default.
• W1925979205 countsByYear W19259792052016 @default.
• W1925979205 countsByYear W19259792052017 @default.
• W1925979205 countsByYear W19259792052018 @default.
• W1925979205 countsByYear W19259792052019 @default.
• W1925979205 countsByYear W19259792052020 @default.
• W1925979205 countsByYear W19259792052021 @default.
• W1925979205 countsByYear W19259792052022 @default.
• W1925979205 countsByYear W19259792052023 @default.
• W1925979205 crossrefType "journal-article" @default.
• W1925979205 hasAuthorship W1925979205A5037024512 @default.
• W1925979205 hasAuthorship W1925979205A5064447926 @default.
• W1925979205 hasConcept C109663097 @default.
• W1925979205 hasConcept C121332964 @default.
• W1925979205 hasConcept C147597530 @default.
• W1925979205 hasConcept C154238967 @default.
• W1925979205 hasConcept C159063594 @default.
• W1925979205 hasConcept C159467904 @default.
• W1925979205 hasConcept C163258240 @default.
• W1925979205 hasConcept C177801218 @default.
• W1925979205 hasConcept C178790620 @default.
• W1925979205 hasConcept C185592680 @default.
• W1925979205 hasConcept C204530211 @default.
• W1925979205 hasConcept C44280652 @default.
• W1925979205 hasConcept C45119746 @default.
• W1925979205 hasConcept C555008776 @default.
• W1925979205 hasConcept C59593255 @default.
• W1925979205 hasConcept C72688512 @default.
• W1925979205 hasConcept C75079739 @default.
• W1925979205 hasConcept C97355855 @default.
• W1925979205 hasConceptScore W1925979205C109663097 @default.
• W1925979205 hasConceptScore W1925979205C121332964 @default.
• W1925979205 hasConceptScore W1925979205C147597530 @default.
• W1925979205 hasConceptScore W1925979205C154238967 @default.
• W1925979205 hasConceptScore W1925979205C159063594 @default.
• W1925979205 hasConceptScore W1925979205C159467904 @default.
• W1925979205 hasConceptScore W1925979205C163258240 @default.
• W1925979205 hasConceptScore W1925979205C177801218 @default.
• W1925979205 hasConceptScore W1925979205C178790620 @default.
• W1925979205 hasConceptScore W1925979205C185592680 @default.
• W1925979205 hasConceptScore W1925979205C204530211 @default.
• W1925979205 hasConceptScore W1925979205C44280652 @default.
• W1925979205 hasConceptScore W1925979205C45119746 @default.
• W1925979205 hasConceptScore W1925979205C555008776 @default.
• W1925979205 hasConceptScore W1925979205C59593255 @default.
• W1925979205 hasConceptScore W1925979205C72688512 @default.
• W1925979205 hasConceptScore W1925979205C75079739 @default.
• W1925979205 hasConceptScore W1925979205C97355855 @default.
• W1925979205 hasIssue "28" @default.
• W1925979205 hasLocation W19259792051 @default.
• W1925979205 hasLocation W19259792052 @default.
• W1925979205 hasOpenAccess W1925979205 @default.

• next