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- W1926421428 abstract "Reactions of [MCl2(L–L)], M = Pt, Pd; L–L = bis(diphenylphosphino)methane (dppm) or bis(diphenylphosphino)ethane (dppe), with NaC5H4SN in a 1 : 2 molar ratio lead to mononuclear species [M(S-C5H4SN)2(P–P)], M = Pt; L–L = dppm (1) or dppe (2) and M = Pd; L–L = dppe (3), as well as to the dinuclear [Pd2(μ2-S,N-C5H4SN)(μ2-κ2S-C5H4SN)(μ2-dppm)(S-C5H4SN)2] (4). In contrast, reaction of [MCl2(dppm)] with NaC5H4SN in a 1 : 1 molar ratio leads to [Pd2(μ2-S,N-C5H4SN)3(μ2-dppm)]Cl (5) and trans-[Pt(S-C5H4SN)2(PPh2Me)2] (6) respectively. The latter is formed in low yield by cleavage of the dppm ligand. The dinuclear derivatives 4 and 5 present an A-frame and lantern structure, respectively. The former showing three different co-ordination modes in the same molecule with a short Pd–Pd distance of 2.9583 (9) Å and the latter with three bridging S,N thionate ligands showing a shorter Pd–Pd distance of 2.7291 (13) Å. Both distances could be imposed by the bridging ligands or point to some sort of metal–metal interaction." @default.
- W1926421428 created "2016-06-24" @default.
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- W1926421428 date "2006-01-01" @default.
- W1926421428 modified "2023-10-03" @default.
- W1926421428 title "Pyridine-2-thionate as a versatile ligand in Pd(<scp>ii</scp>) and Pt(<scp>ii</scp>) chemistry: the presence of three different co-ordination modes in [Pd<sub>2</sub>(μ<sub>2</sub>-S,N-C<sub>5</sub>H<sub>4</sub>SN)(μ<sub>2</sub>-κ<sup>2</sup>S-C<sub>5</sub>H<sub>4</sub>SN)(μ<sub>2</sub>-dppm)(S-C<sub>5</sub>H<sub>4</sub>SN)<sub>2</sub>]" @default.
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- W1926421428 doi "https://doi.org/10.1039/b508438e" @default.
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