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• W1927002568 abstract "Abstract Gephyrotoxin 287C, a bioactive alkaloid bearing a perhydropyrrolo[1,2‐ a ]quinoline skeleton with five stereocenters, is an attractive target for synthetic organic chemistry. We achieved an enantioselective total synthesis of (+)‐gephyrotoxin 287C, for which the key steps were palladium‐catalyzed asymmetric allylic amination using a chiral diaminophosphine oxide (DIAPHOX) preligand, diastereoselective intramolecular Mannich reaction, and tin tetrachloride‐catalyzed diastereoselective conjugate addition/protonation. magnified image" @default.
• W1927002568 created "2016-06-24" @default.
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• W1927002568 date "2015-07-29" @default.
• W1927002568 modified "2023-10-18" @default.
• W1927002568 title "Enantioselective Total Synthesis of (+)-Gephyrotoxin 287C" @default.
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• W1927002568 doi "https://doi.org/10.1002/adsc.201500378" @default.
• W1927002568 hasPublicationYear "2015" @default.
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