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- W1930721567 abstract "Axially linked trifluoroethoxy (TFEO)-coated subphthalocyanine (SubPc) homo- and heterodimers were synthesized by two different axial ligand substitution methods. TFEO-SubPc homodimers were obtained directly from TFEO-SubPc boron chloride with o-, m-, and p-hydroquinones, while TFEO-SubPc heterodimers were synthesized via stepwise construction using a combination of the TFEO method and Torres' triflate method. The optical properties of the dimers obtained were investigated using UV-Vis and fluorescence spectrometry. Electron transfer was observed in the heterodimers, and TFEO-SubPc acted as an electron acceptor in the process. The electron transfer process differs depending on the o-, m-, and p-geometries of the hydroquinone linker, and is supported by computational calculations." @default.
- W1930721567 created "2016-06-24" @default.
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- W1930721567 date "2015-01-01" @default.
- W1930721567 modified "2023-09-26" @default.
- W1930721567 title "Synthesis and optical properties of subphthalocyanine homo- and heterodimers axially connected via a hydroquinone linker" @default.
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- W1930721567 doi "https://doi.org/10.1039/c5dt02279g" @default.
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