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• W1931617008 endingPage "2083" @default.
• W1931617008 startingPage "2077" @default.
• W1931617008 abstract "An unprecedented transfer silylation of alcohols catalyzed by the strong Lewis acid B(C6F5)3 is described. Gaseous Me3SiH is released in situ by B(C6F5)3-catalyzed decomposition of 3-trimethylsilylcyclohexa-1,4-diene and subsequently reacts with an alcohol in a dehydrogenative Si–O coupling promoted by the same boron catalyst. Benzene and dihydrogen are formed during the reaction, but no salt waste is. This expedient protocol is applicable to several silicon groups, and the preparation of trimethylsilyl ethers presented here is potentially useful for alcohol derivatization prior to GLC analysis." @default.
• W1931617008 created "2016-06-24" @default.
• W1931617008 creator A5002792140 @default.
• W1931617008 creator A5051049163 @default.
• W1931617008 creator A5090050558 @default.
• W1931617008 date "2014-01-30" @default.
• W1931617008 modified "2023-10-02" @default.
• W1931617008 title "Salt-Free Preparation of Trimethylsilyl Ethers by B(C₆F₅)₃-Catalyzed Transfer Silylation by Using a Me₃SiH Surrogate" @default.
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• W1931617008 doi "https://doi.org/10.1002/ejoc.201301840" @default.
• W1931617008 hasPublicationYear "2014" @default.
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