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- W1932020121 abstract "Abstract 1,2‐Diols 3 have been synthesized by the aldol addition of hydroxy esters 1 to propargyl aldehydes 2 in dichloromethane. These 1,2‐diols undergo a base‐initiated rearrangement under mild conditions in methanol with an unusual 1,2‐alkyl shift to afford interesting α,β‐unsaturated γ‐butyrolactones 4 . A possible mechanism is postulated on the basis of experimental evidence and the results of DFT calculations." @default.
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- W1932020121 date "2014-09-17" @default.
- W1932020121 modified "2023-10-12" @default.
- W1932020121 title "Synthesis of 1,2-Diols and Their Base-Initiated Rearrangement to Butyrolactones" @default.
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- W1932020121 doi "https://doi.org/10.1002/ejoc.201402853" @default.
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