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- W1933121159 endingPage "4793" @default.
- W1933121159 startingPage "4787" @default.
- W1933121159 abstract "Abstract The isomeric tetrahydroxylated pillar[5]arenes were synthesized through partial oxidation of 1,4‐dimethoxypillar[5]arene or 1,4‐dimethoxypillar[4]arene[1]quinone by (NH 4 ) 2 [Ce(NO 3 ) 6 ] and then reduction by Na 2 S 2 O 4 . The intermediate 1,4‐dimethoxypillar[3]arene[2]quinones have two constitutional isomers. The yield of the 1,3‐isomer 1 can reach 42 %, and was far higher than that of the 1,2‐isomer 2 (formed in trace amounts). The approach provides an efficient way to prepare constitutional‐isomeric selectively functionalized pillar[5]arenes 3 and 4 . Furthermore, the host–guest complexation of 3 and 4 with a bis(imidazolium) salt was investigated." @default.
- W1933121159 created "2016-06-24" @default.
- W1933121159 creator A5029621989 @default.
- W1933121159 creator A5067872317 @default.
- W1933121159 date "2013-06-21" @default.
- W1933121159 modified "2023-10-10" @default.
- W1933121159 title "Selective Preparation of Isomeric Tetrahydroxypillar[5]arenes and Pillar[3]arene[2]quinones" @default.
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- W1933121159 doi "https://doi.org/10.1002/ejoc.201300455" @default.
- W1933121159 hasPublicationYear "2013" @default.
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