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- W1934982078 abstract "Abstract The Bi 12.5 Sm 1.5 ReO 24.5 phase has been synthesized for the first time. The preparation of Bi 12.5 Sm 1.5 ReO 24.5 has been carried out by solid-state reaction from Bi 2 O 3 , Sm 2 O 3 , and Re 2 O 7 . The X-ray measurements have showed that Bi 12.5 Sm 1.5 ReO 24.5 was cubic structure (space group Fm3m ). The standard molar enthalpy of formation of Bi 12.5 Sm 1.5 ReO 24.5 has been determined by solution calorimetry combining the enthalpies of dissolution of Bi 12.5 Sm 1.5 ReO 24.5 and 6.25Bi 2 O 3 + 0.75Sm 2 O 3 + 0.5Re 2 O 7 mixture in 2 M HCl and literature data. It has been obtained that above-mentioned phase is thermodynamically stable with respect to their decomposition into binary oxides at room temperatures." @default.
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- W1934982078 date "2014-01-01" @default.
- W1934982078 modified "2023-09-27" @default.
- W1934982078 title "Thermochemical investigation of δ-Bi2O3 doped by Re2O7 and Sm2O3" @default.
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- W1934982078 doi "https://doi.org/10.1016/j.tca.2013.08.021" @default.
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