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- W1935475003 abstract "Abstract N ‐[3‐(Phenyltellanyl)propyl]picolinamide (HL1) or N ‐[ N″ , N″ ‐methyl(phenyl)aminothiocarbonyl]‐ N′ ‐[3‐(phenyltellanyl)propyl]benzamidine (HL2) react with equivalent amounts of PtCl 2 or PdCl 2 with formation of neutral [MCl(L1‐κ N , N′ , Te )] or [MCl(L2‐κ S , N , Te )] chelates. A corresponding reaction of HL2 with HgCl 2 results in the formation of [HgCl 2 (HL2‐κ S , Te )]. Treatment of [PtCl(L1‐ N , N′ , Te )] with elemental iodine results in the exclusive oxidation of the metal ion and the platinum(IV) complex [PtI 3 (L1‐κ N , N′ , Te )] could be isolated in reasonable amounts. A decomposition of the tellurium‐containing ligand and the formation of [PdI 2 (PhTeI) 2 ] was observed during a similar procedure with the corresponding palladium complex. The bonding situation inside the latter compound was analyzed through density functional theory calculations." @default.
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- W1935475003 date "2015-07-08" @default.
- W1935475003 modified "2023-10-10" @default.
- W1935475003 title "Pt, Pd and Hg Complexes with Potentially Tridentate Telluroether Ligands" @default.
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- W1935475003 doi "https://doi.org/10.1002/ejic.201500365" @default.
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