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• W1936600521 startingPage "10829" @default.
• W1936600521 abstract "The treatment of bis[(dialkylamino)cyclopropenimines] with dihalophosphines in the presence of trimethylsilyl trifluoromethanesulfonate (TMSOTf) to form diimine-stabilized P(III) -centered dications is reported. The structures of the new compounds were determined by using X-ray diffraction analysis and their donor abilities as ligands evaluated through electrochemical methods. Despite the two positive charges that they bear, these compounds depict intermediate behavior between that of phosphines and phosphites. The coordination of the [L2 PR](2+) moiety to Au(I) and Ag(I) is also reported. Even more surprisingly, these phosphorus centers can be oxidized to the corresponding P(V) dications in the presence of strong oxidants such as peroxides or XeF2 ." @default.
• W1936600521 created "2016-06-24" @default.
• W1936600521 creator A5011726242 @default.
• W1936600521 creator A5058517447 @default.
• W1936600521 creator A5060653950 @default.
• W1936600521 date "2015-06-19" @default.
• W1936600521 modified "2023-10-18" @default.
• W1936600521 title "Bis[(dialkylamino)cyclopropenimine]-Stabilized P^III- and P^V-Centered Dications" @default.
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• W1936600521 doi "https://doi.org/10.1002/chem.201500688" @default.
• W1936600521 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26097007" @default.
• W1936600521 hasPublicationYear "2015" @default.
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