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• W1936931728 abstract "Abstract Functionalization of the polyaromatic shell of a micelle‐like molecular capsule was accomplished by simple functionalization of the amphiphilic subunits composed of a bent bis‐anthracene framework and two trimethylammonium groups. In aqueous solutions, functionalized subunits assemble spontaneously and quantitatively into spherical capsules providing anthracene shells with external diameters of 2–3 nm through hydrophobic and aromatic‐aromatic interactions. The shape and size of the functionalized capsules remain similar to the original, but the emissive intensities increase significantly (up to 5‐fold) by attaching cyano or phenylethynyl groups. Furthermore, the shell‐functionalization drastically enhances the host–guest photophysical properties (up to 8‐fold) in the cavities of the capsules, as estimated by emission intensities from the encapsulated fluorescent dyes." @default.
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• W1936931728 date "2014-10-10" @default.
• W1936931728 modified "2023-10-16" @default.
• W1936931728 title "Micellar Polyaromatic Capsules: Enhanced Emissive Properties through Shell-Functionalization" @default.
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• W1936931728 doi "https://doi.org/10.1002/ejoc.201403136" @default.
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