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• W1937732115 startingPage "2699" @default.
• W1937732115 abstract "Abstract The construction, general performance characteristics and analytical application of a titanium dioxide–modified carbon paste electrode sensitive to hydrogen ions, based on incorporation of titanium dioxide in a carbon paste matrix, is described. The proposed electrochemical sensor exhibits a linear response in the pH range from 2 to 10, at 25 °C, with a sub‐Nernstian slope. The value of a slope is in a direct correlation with the electrode composition – the optimum content of a titanium dioxide in carbon paste is 30 %. Titanium dioxide‐modified carbon paste electrode shows fast response time and reproducibility, confirmed by different compounds determination in both, individual and complex material, namely, in synthetic and real samples. Besides, the electrode shows high selectivity in the presence of the alkali and the alkaline earth ions as Na + , K + , Ca 2+ or Mg 2+ . The standard deviation of the investigated acids (acetic, oxalic, 5‐sulfosalicylic, p ‐toluensulfonic acid, and amino acid‐glycine) and bases ( N , N′ ‐diphenylguanidine and collidine) is less than 1.3 %. The obtained data are compared with those obtained by using a conventional glass pH‐electrode under the same experimental conditions and indicate a high correlation between them." @default.
• W1937732115 created "2016-06-24" @default.
• W1937732115 creator A5034505075 @default.
• W1937732115 creator A5063846468 @default.
• W1937732115 date "2015-07-14" @default.
• W1937732115 modified "2023-10-16" @default.
• W1937732115 title "TiO₂-modified Carbon Paste Electrode as a Sensor for the Assay of Weak Organic Acids/Bases and Complex Matrix Samples" @default.
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• W1937732115 doi "https://doi.org/10.1002/elan.201500323" @default.
• W1937732115 hasPublicationYear "2015" @default.
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