FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1937754489> ?p ?o ?g. }

• W1937754489 endingPage "78" @default.
• W1937754489 startingPage "70" @default.
• W1937754489 abstract "The free radical 4-benzoyloxy-2,2,6,6-tetramethylpiperidine-1-oxyl (4B-TEMPO) is active as an electrocatalyst for primary alcohol oxidations when immobilised at an electrode surface and immersed into an aqueous carbonate buffer solution. In order to improve the catalytic process, a composite film electrode is developed based on (i) carbon microparticles of 2–12 μm diameter to enhance charge transport and (ii) a polymer of intrinsic microporosity (here PIM-EA-TB with a BET surface area of 1027 m2 g−1). The latter acts as a highly rigid molecular framework for the embedded free radical catalyst with simultaneous access to aqueous phase and substrate. The resulting mechanism for the oxidation of primary alcohols is shown to switch in reaction order from first to zeroth with increasing substrate concentration consistent with a kinetically limited process with competing diffusion of charge at the polymer layer-electrode interface (here the “LEk” case in Albery-Hillman notation). Reactivity optimisation and screening for a wider range of primary alcohols in conjunction with DFT-based relative reactivity correlation reveals substrate hydrophobicity as an important factor for enhancing catalytic currents. The PIM-EA-TB host matrix is proposed to control substrate partitioning and thereby catalyst reactivity and selectivity." @default.
• W1937754489 created "2016-06-24" @default.
• W1937754489 creator A5004350279 @default.
• W1937754489 creator A5020022075 @default.
• W1937754489 creator A5032636006 @default.
• W1937754489 creator A5070900555 @default.
• W1937754489 creator A5071095075 @default.
• W1937754489 creator A5087770508 @default.
• W1937754489 creator A5091299146 @default.
• W1937754489 creator A5091537525 @default.
• W1937754489 date "2015-09-29" @default.
• W1937754489 modified "2023-10-14" @default.
• W1937754489 title "Polymer of Intrinsic Microporosity Induces Host-Guest Substrate Selectivity in Heterogeneous 4-Benzoyloxy-TEMPO-Catalysed Alcohol Oxidations" @default.
• W1937754489 cites W1966339380 @default.
• W1937754489 cites W1984129214 @default.
• W1937754489 cites W1986755516 @default.
• W1937754489 cites W1989310901 @default.
• W1937754489 cites W1995456422 @default.
• W1937754489 cites W2002529545 @default.
• W1937754489 cites W2007165520 @default.
• W1937754489 cites W2007324471 @default.
• W1937754489 cites W2008312847 @default.
• W1937754489 cites W2013255212 @default.
• W1937754489 cites W2014934592 @default.
• W1937754489 cites W2018905100 @default.
• W1937754489 cites W2023562556 @default.
• W1937754489 cites W2032746437 @default.
• W1937754489 cites W2033020343 @default.
• W1937754489 cites W2050776309 @default.
• W1937754489 cites W2057485822 @default.
• W1937754489 cites W2064071932 @default.
• W1937754489 cites W2072375490 @default.
• W1937754489 cites W2073355898 @default.
• W1937754489 cites W2074687528 @default.
• W1937754489 cites W2081352969 @default.
• W1937754489 cites W2086179908 @default.
• W1937754489 cites W2087164520 @default.
• W1937754489 cites W2103801464 @default.
• W1937754489 cites W2108961784 @default.
• W1937754489 cites W2119625859 @default.
• W1937754489 cites W2137892678 @default.
• W1937754489 cites W2165618882 @default.
• W1937754489 cites W2168547550 @default.
• W1937754489 cites W2170720794 @default.
• W1937754489 cites W2317425816 @default.
• W1937754489 doi "https://doi.org/10.1007/s12678-015-0284-8" @default.
• W1937754489 hasPublicationYear "2015" @default.
• W1937754489 type Work @default.
• W1937754489 sameAs 1937754489 @default.
• W1937754489 citedByCount "16" @default.
• W1937754489 countsByYear W19377544892016 @default.
• W1937754489 countsByYear W19377544892017 @default.
• W1937754489 countsByYear W19377544892018 @default.
• W1937754489 countsByYear W19377544892019 @default.
• W1937754489 countsByYear W19377544892020 @default.
• W1937754489 countsByYear W19377544892021 @default.
• W1937754489 countsByYear W19377544892022 @default.
• W1937754489 countsByYear W19377544892023 @default.
• W1937754489 crossrefType "journal-article" @default.
• W1937754489 hasAuthorship W1937754489A5004350279 @default.
• W1937754489 hasAuthorship W1937754489A5020022075 @default.
• W1937754489 hasAuthorship W1937754489A5032636006 @default.
• W1937754489 hasAuthorship W1937754489A5070900555 @default.
• W1937754489 hasAuthorship W1937754489A5071095075 @default.
• W1937754489 hasAuthorship W1937754489A5087770508 @default.
• W1937754489 hasAuthorship W1937754489A5091299146 @default.
• W1937754489 hasAuthorship W1937754489A5091537525 @default.
• W1937754489 hasBestOaLocation W19377544892 @default.
• W1937754489 hasConcept C111368507 @default.
• W1937754489 hasConcept C114157696 @default.
• W1937754489 hasConcept C118792377 @default.
• W1937754489 hasConcept C127313418 @default.
• W1937754489 hasConcept C127413603 @default.
• W1937754489 hasConcept C142724271 @default.
• W1937754489 hasConcept C147789679 @default.
• W1937754489 hasConcept C161790260 @default.
• W1937754489 hasConcept C17525397 @default.
• W1937754489 hasConcept C178790620 @default.
• W1937754489 hasConcept C184651966 @default.
• W1937754489 hasConcept C185592680 @default.
• W1937754489 hasConcept C204787440 @default.
• W1937754489 hasConcept C2776910235 @default.
• W1937754489 hasConcept C2777289219 @default.
• W1937754489 hasConcept C33989665 @default.
• W1937754489 hasConcept C42360764 @default.
• W1937754489 hasConcept C52859227 @default.
• W1937754489 hasConcept C71924100 @default.
• W1937754489 hasConceptScore W1937754489C111368507 @default.
• W1937754489 hasConceptScore W1937754489C114157696 @default.
• W1937754489 hasConceptScore W1937754489C118792377 @default.
• W1937754489 hasConceptScore W1937754489C127313418 @default.
• W1937754489 hasConceptScore W1937754489C127413603 @default.
• W1937754489 hasConceptScore W1937754489C142724271 @default.
• W1937754489 hasConceptScore W1937754489C147789679 @default.
• W1937754489 hasConceptScore W1937754489C161790260 @default.
• W1937754489 hasConceptScore W1937754489C17525397 @default.
• W1937754489 hasConceptScore W1937754489C178790620 @default.
• W1937754489 hasConceptScore W1937754489C184651966 @default.

• next