FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1937843574> ?p ?o ?g. }

• W1937843574 endingPage "2433" @default.
• W1937843574 startingPage "2429" @default.
• W1937843574 abstract "Rate constants for solvolysis involving the displacement of chloride from the carbonyl carbon of diphenylacetyl chloride ((C6H5)2CHCOCl, 1) in ethanol, methanol, aqueous binary mixtures incorporating ethanol, methanol, acetone, 2,2,2-trifluoroethanol (TFE), and 1,1,1,3,3,3-hexafluoro-2-propanol, and binary mixtures of TFE with ethanol are reported. The kinetic data obtained from the reactions in 34 different solvents and solvent mixtures gave an extended Grunwald–Winstein correlation with the l value of 0.76 ± 0.06, the m value of 0.34 ± 0.04, and the correlation coefficient (R2) of 0.932. The appreciable values for both l and m suggest that the bond formation is ahead of the bond breaking with an SN2 mechanism, and the l/m ratio of 2.2 is also in the range of values found for SN2 reaction. This interpretation is further supported by the activation parameters, i.e., relatively small positive ΔH≠ (7.7–16.3 kcal/mol) values and large negative ΔS≠ (−24.6 to −53.4 cal/mol/K) values, and the solvent kinetic isotope effect (1.62)." @default.
• W1937843574 created "2016-06-24" @default.
• W1937843574 creator A5054062795 @default.
• W1937843574 creator A5066992992 @default.
• W1937843574 date "2015-08-28" @default.
• W1937843574 modified "2023-10-16" @default.
• W1937843574 title "Correlation of Rates of Solvolysis of Diphenylacetyl Chloride Using Extended Grunwald-Winstein Equation" @default.
• W1937843574 cites W1532377613 @default.
• W1937843574 cites W1745554122 @default.
• W1937843574 cites W1979317988 @default.
• W1937843574 cites W1980131925 @default.
• W1937843574 cites W1986775142 @default.
• W1937843574 cites W1997444615 @default.
• W1937843574 cites W2009221483 @default.
• W1937843574 cites W2010890233 @default.
• W1937843574 cites W2015503021 @default.
• W1937843574 cites W2026171459 @default.
• W1937843574 cites W2030970501 @default.
• W1937843574 cites W2047834511 @default.
• W1937843574 cites W2063762764 @default.
• W1937843574 cites W2066064658 @default.
• W1937843574 cites W2078348124 @default.
• W1937843574 cites W2088036091 @default.
• W1937843574 cites W2088547129 @default.
• W1937843574 cites W2125802676 @default.
• W1937843574 cites W2138085173 @default.
• W1937843574 cites W2170001791 @default.
• W1937843574 cites W2323189773 @default.
• W1937843574 cites W2326824234 @default.
• W1937843574 cites W2335217515 @default.
• W1937843574 cites W4211081305 @default.
• W1937843574 doi "https://doi.org/10.1002/bkcs.10465" @default.
• W1937843574 hasPublicationYear "2015" @default.
• W1937843574 type Work @default.
• W1937843574 sameAs 1937843574 @default.
• W1937843574 citedByCount "2" @default.
• W1937843574 countsByYear W19378435742019 @default.
• W1937843574 countsByYear W19378435742020 @default.
• W1937843574 crossrefType "journal-article" @default.
• W1937843574 hasAuthorship W1937843574A5054062795 @default.
• W1937843574 hasAuthorship W1937843574A5066992992 @default.
• W1937843574 hasConcept C113196181 @default.
• W1937843574 hasConcept C121332964 @default.
• W1937843574 hasConcept C147789679 @default.
• W1937843574 hasConcept C148898269 @default.
• W1937843574 hasConcept C155647269 @default.
• W1937843574 hasConcept C178790620 @default.
• W1937843574 hasConcept C179104552 @default.
• W1937843574 hasConcept C184651966 @default.
• W1937843574 hasConcept C185592680 @default.
• W1937843574 hasConcept C2778695967 @default.
• W1937843574 hasConcept C2779293432 @default.
• W1937843574 hasConcept C2779607525 @default.
• W1937843574 hasConcept C2780161600 @default.
• W1937843574 hasConcept C2780471494 @default.
• W1937843574 hasConcept C2781213060 @default.
• W1937843574 hasConcept C58364064 @default.
• W1937843574 hasConcept C62520636 @default.
• W1937843574 hasConcept C69928629 @default.
• W1937843574 hasConcept C93391505 @default.
• W1937843574 hasConcept C94412978 @default.
• W1937843574 hasConcept C96765332 @default.
• W1937843574 hasConceptScore W1937843574C113196181 @default.
• W1937843574 hasConceptScore W1937843574C121332964 @default.
• W1937843574 hasConceptScore W1937843574C147789679 @default.
• W1937843574 hasConceptScore W1937843574C148898269 @default.
• W1937843574 hasConceptScore W1937843574C155647269 @default.
• W1937843574 hasConceptScore W1937843574C178790620 @default.
• W1937843574 hasConceptScore W1937843574C179104552 @default.
• W1937843574 hasConceptScore W1937843574C184651966 @default.
• W1937843574 hasConceptScore W1937843574C185592680 @default.
• W1937843574 hasConceptScore W1937843574C2778695967 @default.
• W1937843574 hasConceptScore W1937843574C2779293432 @default.
• W1937843574 hasConceptScore W1937843574C2779607525 @default.
• W1937843574 hasConceptScore W1937843574C2780161600 @default.
• W1937843574 hasConceptScore W1937843574C2780471494 @default.
• W1937843574 hasConceptScore W1937843574C2781213060 @default.
• W1937843574 hasConceptScore W1937843574C58364064 @default.
• W1937843574 hasConceptScore W1937843574C62520636 @default.
• W1937843574 hasConceptScore W1937843574C69928629 @default.
• W1937843574 hasConceptScore W1937843574C93391505 @default.
• W1937843574 hasConceptScore W1937843574C94412978 @default.
• W1937843574 hasConceptScore W1937843574C96765332 @default.
• W1937843574 hasIssue "10" @default.
• W1937843574 hasLocation W19378435741 @default.
• W1937843574 hasOpenAccess W1937843574 @default.
• W1937843574 hasPrimaryLocation W19378435741 @default.
• W1937843574 hasRelatedWork W1967685062 @default.
• W1937843574 hasRelatedWork W1995131647 @default.
• W1937843574 hasRelatedWork W2007723396 @default.
• W1937843574 hasRelatedWork W2060083339 @default.
• W1937843574 hasRelatedWork W2082814785 @default.
• W1937843574 hasRelatedWork W2142638755 @default.
• W1937843574 hasRelatedWork W2326406941 @default.
• W1937843574 hasRelatedWork W2381476793 @default.
• W1937843574 hasRelatedWork W2505130153 @default.
• W1937843574 hasRelatedWork W2951314393 @default.
• W1937843574 hasVolume "36" @default.

• next