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• W1938065426 abstract "Abstract Independent control of halide substitution at six of the seven naphthalene positions of 2‐arylnaphthalenes is achieved through the regioselective benzannulation of chloro‐, bromo‐, and iodoalkynes. The modularity of this approach is demonstrated through the preparation of 44 polyheterohalogenated naphthalene products, most of which are difficult to access through known naphthalene syntheses. The outstanding regioselectivity of the reaction is both predictable and proven unambiguously by single‐crystal X‐ray diffraction for many examples. This synthetic method enables the rapid preparation of complex aromatic systems poised for further derivatization using established cross‐coupling methods. The power and versatility of this approach makes substituted naphthalenes highly attractive building blocks for new organic materials and diversity‐oriented synthesis." @default.
• W1938065426 created "2016-06-24" @default.
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• W1938065426 date "2015-10-30" @default.
• W1938065426 modified "2023-10-17" @default.
• W1938065426 title "Regioselective Synthesis of Polyheterohalogenated Naphthalenes via the Benzannulation of Haloalkynes" @default.
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• W1938065426 doi "https://doi.org/10.1002/chem.201503418" @default.
• W1938065426 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26515732" @default.
• W1938065426 hasPublicationYear "2015" @default.
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