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• W1938744564 endingPage "9549" @default.
• W1938744564 startingPage "9544" @default.
• W1938744564 abstract "Abstract A cobalt‐catalyzed dual annulation reaction for the synthesis of variously substituted indenoisoquinolinones from 2‐bromobenzaldehydes, amines, and methyl 2‐(ethynyl)benzoates has been developed. This method could also be applied to the synthesis of an array of highly functionalized bioactive indenoisoquinolinones and their derivatives. A possible mechanism of the cobalt catalysis is proposed, involving imine formation from bromobenzaldehyde and the amine, followed by a series of oxidative addition, alkyne insertion, cyclization reactions, and carbon–carbon double‐bond migration. The regioselective alkyne insertion plays an important role for the success of the second annulation." @default.
• W1938744564 created "2016-06-24" @default.
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• W1938744564 date "2015-05-18" @default.
• W1938744564 modified "2023-10-11" @default.
• W1938744564 title "Cobalt-Catalyzed Dual Annulation of<i>o</i>-Halobenzaldimine with Alkyne: A Powerful Route toward Bioactive Indenoisoquinolinones" @default.
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• W1938744564 doi "https://doi.org/10.1002/chem.201501152" @default.
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• W1938744564 hasPublicationYear "2015" @default.
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