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• W1939196777 endingPage "54" @default.
• W1939196777 startingPage "49" @default.
• W1939196777 abstract "A SCO iron(III) complex [FeIII(Him)2(4MeOhapen)]CF3SO3 was synthesized, where Him = imidazole and 4-MeOhapen = N,N′-bis(2-oxy-4-methoxyacetophenylidene)ethylenediamine. FeIII ion has an octahedral coordination geometry with N2O2 donor atoms of the equatorial tetradentate ligand (4-MeOhapen) and two nitrogen atoms of two imidazoles (Him) at the axial positions. The adjacent cations are bridged by CF3SO3− ion through NH⋯O hydrogen bonds between Him and CF3SO3− to give a one-dimensional chain structure {[FeIII(Him)2(4MeO-hapen)]CF3SO3}1∞. The magnetic susceptibility measurements showed that complex exhibits an abrupt spin transition between a single HS phase and a symmetry-breaking [HS–HS–HS–LS] phase and another transition around 80 K. The single-crystal X-ray analyses at 296 and 150 K revealed the structures at a single HS and [HS–HS–HS–LS] states." @default.
• W1939196777 created "2016-06-24" @default.
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• W1939196777 date "2016-01-01" @default.
• W1939196777 modified "2023-09-25" @default.
• W1939196777 title "Synthesis, hydrogen-bonded 1D structure, and abrupt spin transition between high-spin (HS) and an ordered [HS–HS–HS–LS] of a mononuclear iron(III) complex [FeIII(Him)2(4-MeOhapen)]CF3SO3 (Him=imidazole, 4-MeOhapen=N,N′-bis(2-oxy-4-methoxyacetophenylidene)ethylenediamine)" @default.
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• W1939196777 doi "https://doi.org/10.1016/j.ica.2015.09.031" @default.
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