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- W1940045924 abstract "Abstract The reactivity of the chlorostannylene [HC(PPh 2 =NSiMe 3 ) 2 SnCl] ( 2 ) with various substrates has been investigated. Compound 2 acts as a two‐electron carbene‐like ligand and forms a complex with W(CO) 5 THF (THF = tetrahydrofuran) to give [HC(PPh 2 =NSiMe 3 ) 2 (Cl)Sn→W(CO) 5 ] ( 4 ). It reacts with benzil and 3,5‐di‐ tert ‐butyl‐ o ‐benzoquinone to give the oxidative cycloaddition products [HC(PPh 2 =NSiMe 3 ) 2 (Cl)Sn{O(Ph)C=C(Ph)O}] ( 5 ) and [HC(PPh 2 =NSiMe 3 ) 2 (Cl)Sn{O(3,5‐di‐ t Bu‐C 6 H 2 )O}] ( 6 ), respectively. The metathesis reaction of 2 with excess sodium azide affords [HC(PPh 2 =NSiMe 3 ) 2 SnN 3 ] ( 7 ). With silver(I) triflate, it forms an ionic triflate salt [HC(PPh 2 =NSiMe 3 ) 2 Sn][CF 3 O 2 SO] ( 8 ), which features an exceptionally long Sn ··· OSO 3 CF 3 distance. It can act as a ligand‐transfer reagent by reacting with [Fe{N(SiMe 3 ) 2 } 2 ] to give [HC(PPh 2 =NSiMe 3 ) 2 Fe(μ‐Cl)] 2 ( 9 ). The X‐ray structures of 2 – 9 have been determined." @default.
- W1940045924 created "2016-06-24" @default.
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- W1940045924 date "2014-06-03" @default.
- W1940045924 modified "2023-10-10" @default.
- W1940045924 title "Reactivity Study of a Chlorostannylene Derived from Bis(iminophosphoranyl)methane" @default.
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- W1940045924 doi "https://doi.org/10.1002/ejic.201402074" @default.
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