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- W1941000419 abstract "Different strategies to encapsulate polymeric chains in ordered hosts are discussed. Pyrrole was polymerized as a model within the crystalline channel system of faujasite (three-dimensional) and mordenite (one-dimensional) zeolite molecular sieves. Polymerization required the presence of an intrazeolite oxidant such as ferric or cupric ions. No reaction was observed with the Na and Fe(II) forms of the zeolites. The yield of the reaction was highest with vapor-phase pyrrole, and it was low in aqueous solvents. The systems were characterized with a combination of electronic, infrared, and Raman spectroscopic data. Electron spin resonance measurements were used to explore the transport properties, and preliminary bulk powder conductivity measurements were performed to evaluate potential conduction paths on the outside of the zeolite crystals. The intrazeolite heteroaromatic polymer chains represent the first example of host-stabilized one-dimensional molecular conductors, or molecular wires." @default.
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- W1941000419 date "1989-05-05" @default.
- W1941000419 modified "2023-10-10" @default.
- W1941000419 title "Stabilization of Conducting Heteroaromatic Polymers in Large-Pore Zeolite Channels" @default.
- W1941000419 doi "https://doi.org/10.1021/ba-1990-0226.ch023" @default.
- W1941000419 hasPublicationYear "1989" @default.
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