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- W194200809 abstract "The kinetic behavior of the Ru/TiO 2 catalyst in the partial oxidation of methane was investigated as a function of temperature and partial pressures of CH 4 , O 2 , CO, CO 2 , H 2 and H 2 O. It has been found that the catalyst promotes, to a large extent, the direct formation of syn-gas from the reaction of methane and oxygen, while the reforming and water-gas shift reactions are negligible under these conditions. It is proposed that the reaction mechanism over the Ru/TiO 2 catalyst involves formation of CO-H 2 and CO 2 -H 2 O in two in series reaction routes, possibly on different active sites of the Ru surface. Part of H 2 , and, to a lesser extent, of CO is consecutively oxidized by adsorbed oxygen to H 2 O and CO 2 giving the final product distribution." @default.
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- W194200809 date "1998-01-01" @default.
- W194200809 modified "2023-10-16" @default.
- W194200809 title "Kinetic behaviour of the Ru/TiO2 catalyst in the reaction of partial oxidation of methane" @default.
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- W194200809 doi "https://doi.org/10.1016/s0167-2991(98)80530-2" @default.
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