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• W1943585718 abstract "Abstract The reactivity of the ynamide tert ‐butyl N ‐ethynyl‐ N ‐phenylcarbamate ( 1 ) in the 1,3‐dipolar cycloaddition (1,3‐DC) with C ‐carboxymethyl‐ N ‐phenylnitrilimine was investigated. This [3+2] cycloaddition affords the 5‐amino pyrazole as a single regioisomer. The obtained cycloadduct has been activated at the 4‐position of the pyrazole ring through bromination and subsequently coupled with a phenyl group under Pd catalysis. A detailed computational study has been performed to fully explain the complete regioselectivity observed." @default.
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• W1943585718 date "2013-10-30" @default.
• W1943585718 modified "2023-10-16" @default.
• W1943585718 title "Experimental and Computational Investigation of the 1,3-Dipolar Cycloaddition of the Ynamide<i>tert</i>-Butyl<i>N</i>-Ethynyl-<i>N</i>-phenylcarbamate with<i>C</i>-Carboxymethyl-<i>N</i>-phenylnitrilimine" @default.
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• W1943585718 doi "https://doi.org/10.1002/ejoc.201301054" @default.
• W1943585718 hasPublicationYear "2013" @default.
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