FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1944239079> ?p ?o ?g. }

• W1944239079 endingPage "459" @default.
• W1944239079 startingPage "429" @default.
• W1944239079 abstract "Conical intersection as a dynamic funnel in nonadiabatic transition dictates many important chemical reaction outputs such as reaction rates, yields, and energy disposals especially for chemical reactions taking place on electronically excited states. Therefore, the energetics and topology of conical intersections have been subjected to intensive theoretical and experimental studies for decades as these things are the keys to understanding and controlling nonadiabatic transitions which are ubiquitous in nature. In this article, we focus on πσ*-mediated photodissociation reactions of thiophenols and thioanisoles. Interestingly, for these chemical systems, the nonadiabatic transition probability can be precisely measured as a function of the excitation energy, giving a great opportunity for spectroscopic characterization of the multi-dimensional conical intersection seam that governs the nonadiabatic transition dynamics of polyatomic molecules. The passage of the reactive flux in the proximity of the conical intersection gives rise to dynamic resonances corresponding to dramatic state-specific increases of the nonadiabatic transition probability. Accordingly, it is found that the electronic and nuclear configurations of the reactive flux and their evolution, coupled to the conical intersection seam, are critical in nonadiabatic transition dynamics. Nonadiabaticity is found to be extremely sensitive to the conformational molecular structure, and this has been demonstrated in the photodissociation dynamics of the chemical derivatives of thiophenol. Intramolecular vibrational redistribution, which is nontrivial in surmounting the reaction barrier, is found to wash out state-specific dynamic resonances, implying the importance of the dynamic interplay between vibrational energy flow and nonadiabatic transition. The experimental results on conical intersection dynamics presented in this review provide many interesting and important issues to be pursued in the near future by both theoreticians and experimentalists." @default.
• W1944239079 created "2016-06-24" @default.
• W1944239079 creator A5009108167 @default.
• W1944239079 creator A5016476290 @default.
• W1944239079 creator A5016866444 @default.
• W1944239079 creator A5021227878 @default.
• W1944239079 creator A5026487799 @default.
• W1944239079 creator A5065730355 @default.
• W1944239079 creator A5071928897 @default.
• W1944239079 creator A5080834994 @default.
• W1944239079 creator A5086764270 @default.
• W1944239079 date "2015-07-03" @default.
• W1944239079 modified "2023-10-18" @default.
• W1944239079 title "Structure and dynamic role of conical intersections in the πσ*-mediated photodissociation reactions" @default.
• W1944239079 cites W1502131880 @default.
• W1944239079 cites W1609350307 @default.
• W1944239079 cites W1611233711 @default.
• W1944239079 cites W1660393481 @default.
• W1944239079 cites W1711790040 @default.
• W1944239079 cites W1938776328 @default.
• W1944239079 cites W1964069776 @default.
• W1944239079 cites W1965574295 @default.
• W1944239079 cites W1968832223 @default.
• W1944239079 cites W1970639190 @default.
• W1944239079 cites W1974768005 @default.
• W1944239079 cites W1978672083 @default.
• W1944239079 cites W1978964851 @default.
• W1944239079 cites W1980002965 @default.
• W1944239079 cites W1980520349 @default.
• W1944239079 cites W1981659415 @default.
• W1944239079 cites W1982007522 @default.
• W1944239079 cites W1983551502 @default.
• W1944239079 cites W1986113347 @default.
• W1944239079 cites W1987245427 @default.
• W1944239079 cites W1987399251 @default.
• W1944239079 cites W1988443173 @default.
• W1944239079 cites W1989807768 @default.
• W1944239079 cites W1990731666 @default.
• W1944239079 cites W1990873079 @default.
• W1944239079 cites W1992710850 @default.
• W1944239079 cites W1995229255 @default.
• W1944239079 cites W1995395712 @default.
• W1944239079 cites W1996576033 @default.
• W1944239079 cites W1998916301 @default.
• W1944239079 cites W2000089562 @default.
• W1944239079 cites W2000166515 @default.
• W1944239079 cites W2001020848 @default.
• W1944239079 cites W2003771289 @default.
• W1944239079 cites W2004294314 @default.
• W1944239079 cites W2004502807 @default.
• W1944239079 cites W2006331199 @default.
• W1944239079 cites W2006542881 @default.
• W1944239079 cites W2006546439 @default.
• W1944239079 cites W2007214694 @default.
• W1944239079 cites W2007520536 @default.
• W1944239079 cites W2007761483 @default.
• W1944239079 cites W2008160899 @default.
• W1944239079 cites W2008225405 @default.
• W1944239079 cites W2009327722 @default.
• W1944239079 cites W2011796905 @default.
• W1944239079 cites W2012952413 @default.
• W1944239079 cites W2017629402 @default.
• W1944239079 cites W2018939430 @default.
• W1944239079 cites W2018998026 @default.
• W1944239079 cites W2020290247 @default.
• W1944239079 cites W2021447758 @default.
• W1944239079 cites W2022368043 @default.
• W1944239079 cites W2023515467 @default.
• W1944239079 cites W2024524738 @default.
• W1944239079 cites W2024744943 @default.
• W1944239079 cites W2025012678 @default.
• W1944239079 cites W2027748968 @default.
• W1944239079 cites W2029833544 @default.
• W1944239079 cites W2030410097 @default.
• W1944239079 cites W2032268994 @default.
• W1944239079 cites W2035216229 @default.
• W1944239079 cites W2035353867 @default.
• W1944239079 cites W2038922877 @default.
• W1944239079 cites W2040654649 @default.
• W1944239079 cites W2042088476 @default.
• W1944239079 cites W2044735268 @default.
• W1944239079 cites W2045610238 @default.
• W1944239079 cites W2046312527 @default.
• W1944239079 cites W2046414937 @default.
• W1944239079 cites W2051210594 @default.
• W1944239079 cites W2051824690 @default.
• W1944239079 cites W2052990074 @default.
• W1944239079 cites W2053977234 @default.
• W1944239079 cites W2057154693 @default.
• W1944239079 cites W2057167269 @default.
• W1944239079 cites W2064587465 @default.
• W1944239079 cites W2066347451 @default.
• W1944239079 cites W2067126405 @default.
• W1944239079 cites W2067339297 @default.
• W1944239079 cites W2068319403 @default.
• W1944239079 cites W2069196706 @default.
• W1944239079 cites W2070638519 @default.
• W1944239079 cites W2073807976 @default.

• next